We have performed density functional theory calculation and tight binging analysis in order to investigate the mechanism for the giant Rashba-type spin splitting (RSS) observed in Bi/Ag(111). We find that local orbital angular momentum induces momentum and spin dependent charge distribution which results in spin-dependent hopping. We show that the spin-dependent interatomic-hopping in Bi/Ag(111) works as a strong effective field and induces the giant RSS, indicating that the giant RSS is driven by hopping, not by a uniform electric field. The effective field from the hopping energy difference amounts to be ~18 V/{AA}. This new perspective on the RSS gives us a hint for the giant RSS mechanism in general and should provide a strategy for designing new RSS materials by controlling spin-dependence of hopping energy between the neighboring atomic layers.
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