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Register a new userCollapsed Tetragonal Phase Transition in LaRu$_2$P$_2$
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The structural properties of LaRu$_2$P$_2$ under external pressure have been studied up to 14 GPa, employing high-energy x-ray diffraction in a diamond-anvil pressure cell. At ambient conditions, LaRu$_2$P$_2$ (I4/mmm) has a tetragonal structure with a bulk modulus of $B=105(2)$ GPa and exhibits superconductivity at $T_c= 4.1$ K. With the application of pressure, LaRu$_2$P$_2$ undergoes a phase transition to a collapsed tetragonal (cT) state with a bulk modulus of $B=175(5)$ GPa. At the transition, the c-lattice parameter exhibits a sharp decrease with a concurrent increase of the a-lattice parameter. The cT phase transition in LaRu$_2$P$_2$ is consistent with a second order transition, and was found to be temperature dependent, increasing from $P=3.9(3)$ GPa at 160 K to $P=4.6(3)$ GPa at 300 K. In total, our data are consistent with the cT transition being near, but slightly above 2 GPa at 5 K. Finally, we compare the effect of physical and chemical pressure in the RRu$_2$P$_2$ (R = Y, La-Er, Yb) isostructural series of compounds and find them to be analogous.
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We present an optical spectroscopy study on P-doped CaFe$_2$As$_2$ which experiences a structural phase transition from tetragonal to collapsed tetragonal (cT) phase near 75 K. The measurement reveals a sudden reduction of low frequency spectral weight and emergence of a new feature near 3200 cm (0.4 eV) in optical conductivity across the transition, indicating an abrupt reconstruction of band structure. The appearance of new feature is related to the interband transition arising from the sinking of hole bands near $Gamma$ point below Fermi level in the cT phase, as expected from the density function theory calculations in combination with the dynamical mean field theory. However, the reduction of Drude spectral weight is at variance with those calculations. The measurement also indicates an absence of the abnormal spectral weight transfer at high energy (near 0.5-0.7 eV) in the cT phase, suggesting a suppression of electron correlation effect.
We present high-energy x-ray diffraction data under applied pressures up to p = 29 GPa, neutron diffraction measurements up to p = 1.1 GPa, and electrical resistance measurements up to p = 5.9 GPa, on SrCo2As2. Our x-ray diffraction data demonstrate that there is a first-order transition between the tetragonal (T) and collapsed-tetragonal (cT) phases, with an onset above approximately 6 GPa at T = 7 K. The pressure for the onset of the cT phase and the range of coexistence between the T and cT phases appears to be nearly temperature independent. The compressibility along the a-axis is the same for the T and cT phases whereas, along the c-axis, the cT phase is significantly stiffer, which may be due to the formation of an As-As bond in the cT phase. Our resistivity measurements found no evidence of superconductivity in SrCo2As2 for p <= 5.9 GPa and T >= 1.8 K. The resistivity data also show signatures consistent with a pressure-induced phase transition for p >= 5.5 GPa. Single-crystal neutron diffraction measurements performed up to 1.1 GPa in the T phase found no evidence of stripe-type or A-type antiferromagnetic ordering down to 10 K. Spin-polarized total-energy calculations demonstrate that the cT phase is the stable phase at high pressure with a c/a ratio of 2.54. Furthermore, these calculations indicate that the cT phase of SrCo2As2 should manifest either A-type antiferromagnetic or ferromagnetic order.
The surprising discovery of tripling the superconducting critical temperature of KFe$_2$As$_2$ at high pressures issued an intriguing question of how the superconductivity in the collapsed tetragonal phase differs from that in the non-collapsed phases of Fe-based superconductors. Here we report $^{89}$Y nuclear magnetic resonance study of YFe$_2$Ge$_{x}$Si$_{2-x}$ compounds whose electronic structure is similar to that of iron-pnictide collapsed tetragonal phases already at ambient pressure. Fe(Ge,Si) layers show strong ferromagnetic spin fluctuations whereas layers are coupled antiferromagnetically -- both positioning the studied family close to a quantum critical point. Next, localized moments attributed either to Fe interstitial or antisite defects may account for magnetic impurity pair-breaking effects thus explaining the substantial variation of superconductivity among different YFe$_2$Ge$_2$ samples.
We use angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations to study the electronic structure of CaFe$_2$As$_2$ in previously unexplored collapsed tetragonal (CT) phase. This unusual phase of the iron arsenic high temperature superconductors was hard to measure as it exists only under pressure. By inducing internal strain, via the post growth, thermal treatment of the single crystals, we were able to stabilize the CT phase at ambient-pressure. We find significant differences in the Fermi surface topology and band dispersion data from the more common orthorhombic-antiferromagnetic or tetragonal-paramagnetic phases, consistent with electronic structure calculations. The top of the hole bands sinks below the Fermi level, which destroys the nesting present in parent phases. The absence of nesting in this phase along with apparent loss of Fe magnetic moment, are now clearly experimentally correlated with the lack of superconductivity in this phase.
We have studied the angular dependent de Haas-van Alphen oscillations of LaRu$_2$P$_2$ using magnetic torque in pulsed magnetic fields up to 60T. The observed oscillation frequencies are in excellent agreement with the geometry of the calculated Fermi surface. The temperature dependence of the oscillation amplitudes reveals effective masses m*($alpha$)=0.71 and m*($beta$)=0.99 m$_e$, which are enhanced over the calculated band mass by $lambda^{cyc}$ of 0.8. We find a similar enhancement $lambda^{gamma} approx 1$ in comparing the measured electronic specific heat ($gamma = 11.5$ mJ/mol K$^2$) with the total DOS from band structure calculations. Remarkably, very similar mass enhancements have been reported in other pnictides LaFe$_2$P$_2$, LaFePO ($T_c approx 4K$), and LaRuPO, independent of whether they are superconducting or not. This is contrary to the common perceptions that the normal state quasi-particle renormalizations reflect the strength of the superconducting paring mechanism and leads to new questions about pairing in isostructural and isoelectronic Ru- and Fe-pnictide superconductors.
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