Perpendicularly magnetized nanowires exhibit distinct domain wall types depending on the geometry. Wide wires contain Bloch walls, narrow wires Neel walls. Here, the transition region is investigated by direct imaging of the wall structure using high-resolution spin-polarized scanning electron microscopy. An achiral intermediate wall type is discovered that is unpredicted by established theoretical models. With the help of micromagnetic simulations, the formation of this novel wall type is explained.