We observe Arp 220, the nearest Ultra-Luminous Infrared Galaxy (ULIRG), over 4 GHz in the K and Ka bands. We provide constraints for the kinematics,morphology, and identify molecular species on scales resolving both nuclei (0.6 or 230 pc). We detect multiple molecular species, including hydroxyl in both cores. We tentatively detect H2O at 21.84 GHz in both nuclei, indicating the likely presence of maser emission. The observed frequency range also contains metastable ammonia transitions from (J,K) = (1,1) to (5,5), as well as the (9,9) inversion line, which, together are a well-known thermometer of dense molecular gas. Furthermore, the non-metastable (4,2) and (10,9) and possibly the (3,1) lines are also detected. We apply a standard temperature analysis to Arp 220. However, the analysis is complicated in that standard LTE assumptions do not hold. There are indications that a substantial fraction of ammonia could be in the non-metastable transitions as opposed to only the metastable ones. Thus, the non-metastable transitions could be essential to constraining the temperature. We compare all of these data to ALMA observations of this source, confirming the outflow previously observed by other tracers in both nuclei.