Using the Binary Population and Spectral Synthesis code BPASS, we have calculated the rates, timescales and mass distributions for binary black hole mergers as a function of metallicity. We consider these in the context of the recently reported 1st LIGO event detection. We find that the event has a very low probability of arising from a stellar population with initial metallicity mass fraction above Z=0.010 (Z>0.5Zsun). Binary black hole merger events with the reported masses are most likely in populations below 0.008 (Z<0.4Zsun). Events of this kind can occur at all stellar population ages from ~3 Myr up to the age of the universe, but constitute only 0.1 to 0.4 per cent of binary BH mergers between metallicities of Z=0.001 to 0.008. However at metallicity Z=0.0001, 26 per cent of binary BH mergers would be expected to have the reported masses. At this metallicity the progenitor merger times can be close to ~10Gyr and rotationally-mixed stars evolving through quasi-homogeneous evolution, due to mass transfer in a binary, dominate the rate. The masses inferred for the black holes in the binary progenitor of GW,150914 are amongst the most massive expected at anything but the lowest metallicities in our models. We discuss the implications of our analysis for the electromagnetic follow-up of future LIGO event detections.