We study, for the first time in a statistically significant and well-defined sample, the relation between the outer-disk ionized-gas metallicity gradients and the presence of breaks in the surface brightness profiles of disk galaxies. SDSS g- and r-band surface brightness, (g- r) color, and ionized-gas oxygen abundance profiles for 324 galaxies within the CALIFA survey are used for this purpose. We perform a detailed light-profile classification finding that 84% of our disks show down- or up-bending profiles (Type II and Type III, respectively) while the remaining 16% are well fitted by one single exponential (Type I). The analysis of the color gradients at both sides of this break shows a U-shaped profile for most Type II galaxies with an average minimum (g- r) color of ~0.5 mag and a ionized-gas metallicity flattening associated to it only in the case of low-mass galaxies. More massive systems show a rather uniform negative metallicity gradient. The correlation between metallicity flattening and stellar mass results in p-values as low as 0.01. Independently of the mechanism having shaped the outer light profiles of these galaxies, stellar migration or a previous episode of star formation in a shrinking star-forming disk, it is clear that the imprint in their ionized-gas metallicity was different for low- and high-mass Type II galaxies. In the case of Type III disks, a positive correlation between the change in color and abundance gradient is found (the null hypothesis is ruled out with a p-value of 0.02), with the outer disks of Type III galaxies with masses $leq$10$^{10}$ M$_{odot}$ showing a weak color reddening or even a bluing. This is interpreted as primarily due to a mass down-sizing effect on the population of Type III galaxies having recently experienced an enhanced inside-out growth.
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