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Collisions of small ice particles under microgravity conditions (II): Does the chemical composition of the ice change the collisional properties?

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 Added by Catherine Hill
 Publication date 2015
  fields Physics
and research's language is English




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Context: Understanding the collisional properties of ice is important for understanding both the early stages of planet formation and the evolution of planetary ring systems. Simple chemicals such as methanol and formic acid are known to be present in cold protostellar regions alongside the dominant water ice; they are also likely to be incorporated into planets which form in protoplanetary disks, and planetary ring systems. However, the effect of the chemical composition of the ice on its collisional properties has not yet been studied. Aims: Collisions of 1.5 cm ice spheres composed of pure crystalline water ice, water with 5% methanol, and water with 5% formic acid were investigated to determine the effect of the ice composition on the collisional outcomes. Methods: The collisions were conducted in a dedicated experimental instrument, operated under microgravity conditions, at relative particle impact velocities between 0.01 and 0.19 m s^-1, temperatures between 131 and 160 K and a pressure of around 10^-5 mbar. Results: A range of coefficients of restitution were found, with no correlation between this and the chemical composition, relative impact velocity, or temperature. Conclusions: We conclude that the chemical composition of the ice (at the level of 95% water ice and 5% methanol or formic acid) does not affect the collisional properties at these temperatures and pressures due to the inability of surface wetting to take place. At a level of 5% methanol or formic acid, the structure is likely to be dominated by crystalline water ice, leading to no change in collisional properties. The surface roughness of the particles is the dominant factor in explaining the range of coefficients of restitution.

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Planetisimals are thought to be formed from the solid material of a protoplanetary disk by a process of dust aggregation. It is not known how growth proceeds to kilometre sizes, but it has been proposed that water ice beyond the snowline might affect this process. To better understand collisional processes in protoplanetary disks leading to planet formation, the individual low velocity collisions of small ice particles were investigated. The particles were collided under microgravity conditions on a parabolic flight campaign using a purpose-built, cryogenically cooled experimental setup. The setup was capable of colliding pairs of small ice particles (between 4.7 and 10.8 mm in diameter) together at relative collision velocities of between 0.27 and 0.51 m s ^-1 at temperatures between 131 and 160 K. Two types of ice particle were used: ice spheres and irregularly shaped ice fragments. Bouncing was observed in the majority of cases with a few cases of fragmentation. A full range of normalised impact parameters (b/R = 0.0-1.0) was realised with this apparatus. Coefficients of restitution were evenly spread between 0.08 and 0.65 with an average value of 0.36, leading to a minimum of 58% of translational energy being lost in the collision. The range of coefficients of restitution is attributed to the surface roughness of the particles used in the study. Analysis of particle rotation shows that up to 17% of the energy of the particles before the collision was converted into rotational energy. Temperature did not affect the coefficients of restitution over the range studied.
In this paper we present results of two novel experimental methods to investigate the collisional behavior of individual macroscopic icy bodies. The experiments reported here were conducted in the microgravity environments of parabolic flights and the Bremen drop tower facility. Using a cryogenic parabolic-flight setup, we were able to capture 41 near-central collisions of 1.5-cm-sized ice spheres at relative velocities between 6 and $22 mathrm{cm s^{-1}}$. The analysis of the image sequences provides a uniform distribution of coefficients of restitution with a mean value of $overline{varepsilon} = 0.45$ and values ranging from $varepsilon = 0.06$ to 0.84. Additionally, we designed a prototype drop tower experiment for collisions within an ensemble of up to one hundred cm-sized projectiles and performed the first experiments with solid glass beads. We were able to statistically analyze the development of the kinetic energy of the entire system, which can be well explained by assuming a granular `fluid following Haffs law with a constant coefficient of restitution of $varepsilon = 0.64$. We could also show that the setup is suitable for studying collisions at velocities of $< 5 mathrm{mm s^{-1}}$ appropriate for collisions between particles in Saturns dense main rings.
Models and observations suggest that ice-particle aggregation at and beyond the snowline dominates the earliest stages of planet-formation, which therefore is subject to many laboratory studies. However, the pressure-temperature gradients in proto-planetary disks mean that the ices are constantly processed, undergoing phase changes between different solid phases and the gas phase. Open questions remain as to whether the properties of the icy particles themselves dictate collision outcomes and therefore how effectively collision experiments reproduce conditions in pro- toplanetary environments. Previous experiments often yielded apparently contradictory results on collision outcomes, only agreeing in a temperature dependence setting in above $approx$ 210 K. By exploiting the unique capabilities of the NIMROD neutron scattering instrument, we characterized the bulk and surface structure of icy particles used in collision experiments, and studied how these structures alter as a function of temperature at a constant pressure of around 30 mbar. Our icy grains, formed under liquid nitrogen, undergo changes in the crystalline ice-phase, sublimation, sintering and surface pre-melting as they are heated from 103 to 247 K. An increase in the thickness of the diffuse surface layer from $approx$ 10 to $approx$ 30 {AA} ($approx$ 2.5 to 12 bilayers) proves increased molecular mobility at temperatures above $approx$ 210 K. As none of the other changes tie-in with the temperature trends in collisional outcomes, we conclude that the surface pre-melting phenomenon plays a key role in collision experiments at these temperatures. Consequently, the pressure-temperature environment, may have a larger influence on collision outcomes than previously thought.
134 - B. Gundlach , J. Blum 2014
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