No Arabic abstract
We discuss work performed on a quantum two-level system coupled to multiple thermal baths. To evaluate the work, a measurement of photon exchange between the system and the baths is envisioned. In a realistic scenario, some photons remain unrecorded as they are exchanged with baths that are not accessible to the measurement, and thus only partial information on work and heat is available. The incompleteness of the measurement leads to substantial deviations from standard fluctuation relations. We propose a recovery of these relations, based on including the mutual information given by the counting efficiency of the partial measurement. We further present the experimental status of a possible implementation of the proposed scheme, i.e. a calorimetric measurement of work, currently with nearly single-photon sensitivity.
We study work extraction processes mediated by finite-time interactions with an ambient bath -- emph{partial thermalizations} -- as continuous time Markov processes for two-level systems. Such a stochastic process results in fluctuations in the amount of work that can be extracted and is characterized by the rate at which the system parameters are driven in addition to the rate of thermalization with the bath. We analyze the distribution of work for the case where the energy gap of a two-level system is driven at a constant rate. We derive analytic expressions for average work and lower bound for the variance of work showing that such processes cannot be fluctuation-free in general. We also observe that an upper bound for the Monte Carlo estimate of the variance of work can be obtained using Jarzynskis fluctuation-dissipation relation for systems initially in equilibrium. Finally, we analyse work extraction cycles by modifying the Carnot cycle, incorporating processes involving partial thermalizations and obtain efficiency at maximum power for such finite-time work extraction cycles under different sets of constraints.
We study the equilibrium correlation function of the polaron-dressed tunnelling operator in the dissipative two-state system and compare the asymptoptic dynamics with that of the position correlations. For an Ohmic spectral density with the damping strength $K=1/2$, the correlation functions are obtained in analytic form for all times at any $T$ and any bias. For $K<1$, the asymptotic dynamics is found by using a diagrammatic approach within a Coulomb gas representation. At T=0, the tunnelling or coherence correlations drop as $t^{-2K}$, whereas the position correlations show universal decay $propto t^{-2}$. The former decay law is a signature of unscreened attractive charge-charge interactions, while the latter is due to unscreened dipole-dipole interactions.
We study the dynamical equilibrium correlation function of the polaron-dressed tunneling operator in the dissipative two-state system. Unlike the position operator, this coherence operator acts in the full system-plus-reservoir space. We calculate the relevant modified influence functional and present the exact formal expression for the coherence correlations in the form of a series in the number of tunneling events. For an Ohmic spectral density with the particular damping strength $K=1/2$, the series is summed in analytic form for all times and for arbitrary values of temperature and bias. Using a diagrammatic approach, we find the long-time dynamics in the regime $K<1$. In general, the coherence correlations decay algebraically as $t^{-2K}$ at T=0. This implies that the linear static susceptibility diverges for $Kle 1/2$ as $Tto 0$, whereas it stays finite for $K>1/2$ in this limit. The qualitative differences with respect to the asymptotic behavior of the position correlations are explained.
In this study, the minimum amount of work needed to drive a thermodynamic system from one initial distribution to another in a given time duration is discussed. Equivalently, for given amount of work, the minimum time duration required to complete such a transition is obtained. Results show that the minimum amount of work is used to achieve the following three objectives, to increase the internal energy of the system, to decrease the system entropy, to change the mean position of the system, and with other nonzero part dissipated into environment. To illustrate the results, an example with explicit solutions is presented.
Work extraction from the Gibbs ensemble by a cyclic operation is impossible, as represented by the second law of thermodynamics. On the other hand, the eigenstate thermalization hypothesis (ETH) states that just a single energy eigenstate can describe a thermal equilibrium state. Here we attempt to unify these two perspectives and investigate the second law at the level of individual energy eigenstates, by examining the possibility of extracting work from a single energy eigenstate. Specifically, we performed numerical exact diagonalization of a quench protocol of local Hamiltonians and evaluated the number of work-extractable energy eigenstates. We found that it becomes exactly zero in a finite system size, implying that a positive amount of work cannot be extracted from any energy eigenstate, if one or both of the pre- and the post-quench Hamiltonians are non-integrable. We argue that the mechanism behind this numerical observation is based on the ETH for a non-local observable. Our result implies that quantum chaos, characterized by non-integrability, leads to a stronger version of the second law than the conventional formulation based on the statistical ensembles.