The cosmic background neutrino of temperature 1.9 K affects rates of radiative emission of neutrino pair (RENP) from metastable excited atoms, since its presence blocks the pair emission by the Pauli exclusion principle. We quantitatively investigate how the Pauli blocking distorts the photon energy spectrum and calculate its sensitivity to cosmic parameters such as the neutrino temperature and its chemical potential. Important quantities for high sensitivities to these parameter measurement are found to be the level spacing of atomic de-excitation and the unknown mass value of lightest neutrino, in particular their mutual relation.