The Burst Observer and Optical Transient Exploring System (BOOTES) is a network of telescopes that allows the continuous monitoring of transient astrophysical sources. It was originally devoted to the study of the optical emission from gamma-ray bursts (GRBs) that occur in the Universe. In this paper we show the initial results obtained using the spectrograph COLORES (mounted on BOOTES-2), when observing optical transients (OTs) of diverse nature.