A binary constraint system game is a two-player one-round non-local game defined by a system of Boolean constraints. The game has a perfect quantum strategy if and only if the constraint system has a quantum satisfying assignment [R. Cleve and R. Mittal, arXiv:1209.2729]. We show that several concepts including the quantum chromatic number and the Kochen-Specker sets that arose from different contexts fit naturally in the binary constraint system framework. The structure and complexity of the quantum satisfiability problems for these constraint systems are investigated. Combined with a new construct called the commutativity gadget for each problem, several classic NP-hardness reductions are lifted to their corresponding quant
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