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Register a new userRaman study of CFC tiles extracted from the toroidal pump limiter of Tore Supra
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Cedric Pardanaud
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The structure of six tiles extracted from the erosion and deposition zones (thin and thick deposition) of the Tore Supra toroidal pump limiter (TPL) have been analysed in the framework of the DITS campaign using micro-Raman spectroscopy. This post-mortem analysis gives information on both carbon structure and D content. We have found that the carbon structure is most often similar to that of plasma-deposited hard amorphous carbon layers. The role of the surface temperature during the discharge in the D content is investigated: in all locations where the temperature does not reach more than 500{degree}C the D content seems to be roughly uniform with D/D+C approx 20%.
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We consider two inverse problems related to the tokamak textsl{Tore Supra} through the study of the magnetostatic equation for the poloidal flux. The first one deals with the Cauchy issue of recovering in a two dimensional annular domain boundary magnetic values on the inner boundary, namely the limiter, from available overdetermined data on the outer boundary. Using tools from complex analysis and properties of genereralized Hardy spaces, we establish stability and existence properties. Secondly the inverse problem of recovering the shape of the plasma is addressed thank tools of shape optimization. Again results about existence and optimality are provided. They give rise to a fast algorithm of identification which is applied to several numerical simulations computing good results either for the classical harmonic case or for the data coming from textsl{Tore Supra}.
We revisit here how Raman spectroscopy can be used to estimate the H content in hard hydrogenated amorphous carbon layers. The H content was varied from 2 at.% to 30 at.%, using heat treatments of a a-C:H, from room temperature to 1300 K and was determined independently using ion beam analysis. We examine the correlation of various Raman parameters and the consistency of their thermal evolution with thermo-desorption results. We identify a weak band at 860 cm-1 attributed to H bonded to C(sp2). We show that the HD/HG parameter (Height ratio between the D and G bands) is quasi-linear in the full range of H content and can thus be used to estimate the H content. Conversely, we show that the m/HG parameter (ratio between the photoluminescence background, m, and the height of the G band), often used to estimate the H content, should be used with care, first because it is sensitive to various photoluminescence quenching processes and second because it is not sensitive to H bonded to C(sp2).
Linear and non-linear spectroscopies are powerful tools used to investigate the energetics and dynamics of electronic excited states of both molecules and crystals. While highly accurate emph{ab initio} calculations of molecular spectra can be performed relatively routinely, extending these calculations to periodic systems is challenging. Here, we present calculations of the linear absorption spectrum and pump-probe two-photon photoemission spectra of the naphthalene crystal using equation-of-motion coupled-cluster theory with single and double excitations (EOM-CCSD). Molecular acene crystals are of interest due to the low-energy multi-exciton singlet states they exhibit, which have been studied extensively as intermediates involved in singlet fission. Our linear absorption spectrum is in good agreement with experiment, predicting a first exciton absorption peak at 4.4 eV, and our two-photon photoemission spectra capture the behavior of multi-exciton states, whose double-excitation character cannot be captured by current methods. The simulated pump-probe spectra provide support for existing interpretations of two-photon photoemission in closely-related acene crystals such as tetracene and pentacene.
The sputtering of inside wall components of tokamaks can lead to the injection of supersaturated vapour in the plasma edge. The resulting condensation favours the formation of clusters which can give rise to solid particulates by further accretion. Sputtering discharges are proposed to have highlight on the formation of carbonaceous dust observed in the tokamaks with graphite based wall components. The flux of the sputtered carbon atoms is evaluated in the conditions of our laboratory discharges as well as the evolution of their energy distribution. It is shown that a cooling mechanism occurs through collisions with the discharge argon atoms, leading to a nucleation phase. A comparison between the carbon structure of the resulting dust particles and a dust sample collected in the Tore Supra tokamak is proposed. The structural differences are discussed and can be correlated to specific plasma conditions.
We study the kinetics of the H release from plasma-deposited hydrogenated amorphous carbon films under isothermal heating at 450, 500 and 600 {degree}C for long times up to several days using in situ Raman microscopy. Four Raman parameters are analyzed. They allow the identification of different processes such as the carbon network reorganization and the H release from sp3 or sp2 carbon atoms and the corresponding timescales. Carbon reorganization with aromatization and loss of sp3 hybridization occurs first in 100 minutes at 500 {degree}C. The final organization is similar at all investigated temperatures. Full H release from sp3 carbon occurs on a longer timescale of about 10 hours while H release from sp2 carbon atoms is only partial, even after several days. All these processes occur more rapidly with higher initial H content, in agreement with what is known about the stability of these types of films. A quantitative analysis of these kinetics studies gives valuable information about the microscopic processes at the origin of the H release through the determination of activation energies.
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