We report on the first ten identifications of sources serendipitously detected by the NuSTAR to provide the first sensitive census of the cosmic X-ray background (CXB) source population at >10 keV. We find that these NuSTAR-detected sources are ~100x fainter than those previously detected at >10 keV and have a broad range in redshift and luminosity (z=0.020-2.923 and L_10-40 keV~4x10^{41}-5x10^{45} erg/s); the median redshift and luminosity are z~0.7 and L_10-40 keV~3x10^{44} erg/s, respectively. We characterize these sources on the basis of broad-band ~0.5-32 keV spectroscopy, optical spectroscopy, and broad-band ultraviolet-to-mid-infrared SED analyzes. We find that the dominant source population is quasars with L_10-40 keV>10^{44} erg/s, of which ~50% are obscured with N_H>10^{22} cm^{-2}. However, none of the ten NuSTAR sources are Compton thick (N_H>10^{24} cm^{-2}) and we place a 90% confidence upper limit on the fraction of Compton-thick quasars (L_10-40 keV>10^{44} erg/s) selected at >10 keV of ~33% over the redshift range z=0.5-1.1. We jointly fitted the rest-frame ~10-40 keV data for all of the non-beamed sources with L_10-40 keV>10^{43} erg/s to constrain the average strength of reflection; we find R<1.4 for Gamma=1.8, broadly consistent with that found for local AGNs observed at >10 keV. We also constrain the host galaxy masses and find a median stellar mass of ~10^{11} M_sun, a factor ~5 times higher than the median stellar mass of nearby high-energy selected AGNs, which may be at least partially driven by the order of magnitude higher X-ray luminosities of the NuSTAR sources. Within the low source-statistic limitations of our study, our results suggest that the overall properties of the NuSTAR sources are broadly similar to those of nearby high-energy selected AGNs but scaled up in luminosity and mass.
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