Matched filtering is a popular data analysis framework used to search for gravitational wave signals emitted by compact object binaries. The templates used in matched filtering searches are constructed predominantly from the quadrupolar mode because this mode is the energetically most dominant channel. However, for highly precessing binaries or binaries with moderately large mass ratios, significant power is also carried by higher-order modes. We investigate how the inclusion of higher modes in the templates increases the prospects for detecting gravitational waves. Specifically, we use numerical relativity waveforms from the late inspiral and coalescence of binary black holes to identify mode hierarchies that cover the sky of binary orientations. We show that the ordering in these hierarchies depends on the characteristics of the binary system and the mode strengths. Our study demonstrates that detecting moderately high precessing or unequal mass binaries requires the inclusion of higher modes in the templates banks.