Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userIce polyamorphism in the minimal Mercedes-Benz model of water
134
0
0.0
(
0
)
Added by
Pedro A. S\\'anchez
Publication date
2012
fields
Physics
and research's language is
English
Ask ChatGPT about the research
No Arabic abstract
We investigate ice polyamorphism in the context of the two-dimensional Mercedes-Benz model of water. We find a first-order phase transition between a crystalline phase and a high-density amorphous phase. Furthermore we find a reversible transformation between two amorphous structures of high and low density; however we find this to be a continuous and not an abrupt transition, as the low-density amorphous phase does not show structural stability. We discuss the origin of this behavior and its implications with regard to the minimal generic modeling of polyamorphism.
rate research
Read More
Liquid polyamorphism is the intriguing possibility for a single component substance to exist in multiple liquid phases. We propose a minimal model for this phenomenon. Starting with a classical binary lattice model with critical azeotropy and liquid-liquid demixing, we allow interconversion of the two species, turning the system into a single-component fluid with two states differing in energy and entropy. Changing one interaction parameter allows to continuously switch from a liquid-liquid transition, terminated by a critical point, to a singularity-free scenario, exhibiting water-like anomalies but without polyamorphism. This resolves a controversy about how a liquid-liquid critical point can be found or not in simulations. The model provides a unified theoretical framework to describe supercooled water and a variety of polyamorphic liquids with water-like anomalies.
Artificial spin ice offers the possibility to investigate a variety of dipolar orderings, spin frustrations and ground states. However, the most fascinating aspect is the realization that magnetic charge order can be established without spin order. We have investigated magnetic dipoles arranged on a honeycomb lattice as a function of applied field, using magnetic force microscopy. For the easy direction with the field parallel to one of the three dipole sublattices we observe at coercivity a maximum of spin frustration and simultaneously a maximum of charge order of magnetic monopoles with alternating charges $pm$ 3.
We present a unified understanding for experimentally observed minimal dc conductivity at the Dirac point in weak disordered graphene. First of all, based on the linear response theory, we unravel that randomness or disorder, inevitably inducing momentum dependent corrections in electron self-energy function, naturally yields a sample-dependent minimal conductivity. Taking the long-ranged Gaussian potential as an example, we demonstrate the momentum dependent self-energy function within the Born approximation, and further validate it via numerical simulation using large-scale Lanczos algorithm. The explicit dependence of self-energy on the intensity, concentration and range of potential is critically addressed. Therefore, our results provide a reasonable interpretation of the sample-dependent minimal conductivity observed in graphene samples.
Dielectric spectra (10^4-10^11 Hz) of water and ice at 0 {deg}C are considered in terms of proton conductivity and compared to each other. In this picture, the Debye relaxations, centered at 1/{tau}_W ~ 20 GHz (in water) and 1/{tau}_I ~ 5 kHz (in ice), are seen as manifestations of diffusion of separated charges in the form of H3O+ and OH- ions. The charge separation results from the self-dissociation of H2O molecules, and is accompanied by recombination in order to maintain the equilibrium concentration, N. The charge recombination is a diffusion-controlled process with characteristic lifetimes of {tau}_W and {tau}_I, for water and ice respectively. The static permittivity, {epsilon}(0), is solely determined by N. Both, N and {epsilon}(0), are roughly constant at the water-ice phase transition, and both increase, due to a slowing down of the diffusion rate, as the temperature is lowered. The transformation of the broadband dielectric spectra at 0 {deg}C with the drastic change from {tau}_W to {tau}_I is mainly due to an abrupt (by 0.4 eV) change of the activation energy of the charge diffusion.
Designing and constructing model systems that embody the statistical mechanics of frustration is now possible using nanotechnology. We have arranged nanomagnets on a two-dimensional square lattice to form an artificial spin ice, and studied its fractional excitations, emergent magnetic monopoles, and how they respond to a driving field using X-ray magnetic microscopy. We observe a regime in which the monopole drift velocity is linear in field above a critical field for the onset of motion. The temperature dependence of the critical field can be described by introducing an interaction term into the Bean-Livingston model of field-assisted barrier hopping. By analogy with electrical charge drift motion, we define and measure a monopole mobility that is larger both for higher temperatures and stronger interactions between nanomagnets. The mobility in this linear regime is described by a creep model of zero-dimensional charges moving within a network of quasi-one-dimensional objects.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
