No Arabic abstract
We show that strong enough electric fields can trigger nucleation of needle-shaped metallic embryos in insulators, even when the metal phase is energetically unfavorable without the field. This general phenomenon is due to the gigantic induced dipole moments acquired by the embryos which cause sufficient electrostatic energy gain. Nucleation kinetics are exponentially accelerated by the field-induced suppression of nucleation barriers. Our theory opens the venue of field driven material synthesis. In particular, we briefly discuss synthesis of metallic hydrogen at standard pressure.
The influence of an external static magnetic field (up to 480 mT)on the structural properties of EuTiO$_3$ (ETO) polycrystalline samples was examined by powder XRD at the Elettra synchrotron facilities in the temperature range 100-300K. While the cubic to tetragonal structural phase transition temperature in this magnetic field range remains almost unaffected, significant lattice effects appear at two characteristic temperatures (~200K and 250K), which becomes more pronounced at a critical threshold magnetic field. At ~200K a change in the sign of the magnetostriction is detected attributed to a modification of the local magnetic properties from intrinsic ferromagnetism to intrinsic antiferromagnetism. These data are a clear indication that strong spin-lattice interactions govern also the high temperature phase of ETO and trigger the appearance of magnetic domain formation and novel phase transitions
Since the beginnings of the electronic age, a quest for ever faster and smaller switches has been initiated, since this element is ubiquitous and foundational in any electronic circuit to regulate the flow of current. Mott insulators are promising candidates to meet this need as they undergo extremely fast resistive switching under electric field. However the mechanism of this transition is still under debate. Our spatially-resolved {mu}-XRD imaging experiments carried out on the prototypal Mott insulator (V0.95Cr0.05)2O3 show that the resistive switching is associated with the creation of a conducting filamentary path consisting in an isostructural compressed phase without any chemical nor symmetry change. This clearly evidences that the resistive switching mechanism is inherited from the bandwidth-controlled Mott transition. This discovery might hence ease the development of a new branch of electronics dubbed Mottronics.
We report on the electric field control of magnetic phase transition temperatures in multiferroic Ni3V2O8 thin films. Using magnetization measurements, we find that the phase transition temperature to the canted antiferromagnetic state is suppressed by 0.2 K in an electric field of 30 MV/m, as compared to the unbiased sample. Dielectric measurements show that the transition temperature into the magnetic state associated with ferroelectric order increases by 0.2 K when the sample is biased at 25 MV/m. This electric field control of the magnetic transitions can be qualitatively understood using a mean field model incorporating a tri-linear coupling between the magnetic order parameters and spontaneous polarization.
The nature of the magnetic-field driven superconductor-to-insulator quantum-phase transition in two-dimensional systems at zero temperature has been under debate since the 1980s, and became even more controversial after the observation of a quantum-Griffiths singularity. Whether it is induced by quantum fluctuations of the superconducting phase and the localization of Cooper pairs, or is directly driven by depairing of these pairs, remains an open question. We herein experimentally demonstrate that in weakly-pinning systems and in the limit of infinitely wide films, a sequential superconductor-to-Bose insulator-to-Fermi insulator quantum-phase transition takes place. By limiting their size smaller than the effective penetration depth, however, the vortex interaction alters, and the superconducting state re-enters the Bose-insulating state. As a consequence, one observes a direct superconductor-to-Fermi insulator in the zero-temperature limit. In narrow films, the associated critical-exponent products diverge along the corresponding phase boundaries with increasing magnetic field, which is a hallmark of the quantum-Griffiths singularity.
A pressure-induced simultaneous metal-insulator transition (MIT) and structural-phase transformation in lithium hydride with about 1% volume collapse has been predicted by means of the local density approximation (LDA) in conjunction with an all-electron GW approximation method. The LDA wrongly predicts that the MIT occurs before the structural phase transition. As a byproduct, it is shown that only the use of the generalized-gradient approximation together with the zero-point vibration produces an equilibrium lattice parameter, bulk modulus, and an equation of state that are in excellent agreement with experimental results.