No Arabic abstract
This is an easy-to-read introduction to foundations of deterministic chaos, deterministic diffusion and anomalous diffusion. The first part introduces to deterministic chaos in one-dimensional maps in form of Ljapunov exponents and dynamical entropies. The second part outlines the concept of deterministic diffusion. Then the escape rate formalism for deterministic diffusion, which expresses the diffusion coefficient in terms of the above two chaos quantities, is worked out for a simple map. Part three explains basics of anomalous diffusion by demonstrating the stochastic approach of continuous time random walk theory for an intermittent map. As an example of experimental applications, the anomalous dynamics of biological cell migration is discussed.
This paper presents an {it ab initio} derivation of the expression given by irreversible thermodynamics for the rate of entropy production for different classes of diffusive processes. The first class are Lorentz gases, where non-interacting particles move on a spatially periodic lattice, and collide elastically with fixed scatterers. The second class are periodic systems where $N$ particles interact with each other, and one of them is a tracer particle which diffuses among the cells of the lattice. We assume that, in either case, the dynamics of the system is deterministic and hyperbolic, with positive Lyapunov exponents. This work extends methods originally developed for a chaotic two-dimensional model of diffusion, the multi-baker map, to higher dimensional, continuous time dynamical systems appropriate for systems with one or more moving particles. Here we express the rate of entropy production in terms of hydrodynamic measures that are determined by the fractal properties of microscopic hydrodynamic modes that describe the slowest decay of the system to an equilibrium state.
Consider a chaotic dynamical system generating Brownian motion-like diffusion. Consider a second, non-chaotic system in which all particles localize. Let a particle experience a random combination of both systems by sampling between them in time. What type of diffusion is exhibited by this {em random dynamical system}? We show that the resulting dynamics can generate anomalous diffusion, where in contrast to Brownian normal diffusion the mean square displacement of an ensemble of particles increases nonlinearly in time. Randomly mixing simple deterministic walks on the line we find anomalous dynamics characterised by ageing, weak ergodicity breaking, breaking of self-averaging and infinite invariant densities. This result holds for general types of noise and for perturbing nonlinear dynamics in bifurcation scenarios.
The scaling invariance for chaotic orbits near a transition from unlimited to limited diffusion in a dissipative standard mapping is explained via the analytical solution of the diffusion equation. It gives the probability of observing a particle with a specific action at a given time. We show the diffusion coefficient varies slowly with the time and is responsible to suppress the unlimited diffusion. The momenta of the probability are determined and the behavior of the average squared action is obtained. The limits of small and large time recover the results known in the literature from the phenomenological approach and, as a bonus, a scaling for intermediate time is obtained as dependent on the initial action. The formalism presented is robust enough and can be applied in a variety of other systems including time dependent billiards near a transition from limited to unlimited Fermi acceleration as we show at the end of the letter and in many other systems under the presence of dissipation as well as near a transition from integrability to non integrability.
Methods are presented to evaluate the entropy production rate in stochastic reactive systems. These methods are shown to be consistent with known results from nonequilibrium chemical thermodynamics. Moreover, it is proved that the time average of the entropy production rate can be decomposed into the contributions of the cycles obtained from the stoichiometric matrix in both stochastic processes and deterministic systems. These methods are applied to a complex reaction network constructed on the basis of Roesslers reinjection principle and featuring chemical chaos.
We show that the generalized diffusion coefficient of a subdiffusive intermittent map is a fractal function of control parameters. A modified continuous time random walk theory yields its coarse functional form and correctly describes a dynamical phase transition from normal to anomalous diffusion marked by strong suppression of diffusion. Similarly, the probability density of moving particles is governed by a time-fractional diffusion equation on coarse scales while exhibiting a specific fine structure. Approximations beyond stochastic theory are derived from a generalized Taylor-Green-Kubo formula.