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Register a new userOn the State of Water Ice on Saturns Moon Titan and Implications to Icy Bodies in the Outer Solar System
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The crystalline state of water ice in the Solar System depends on the temperature history of the ice and the influence of energetic particles to which it has been exposed. We measured the infrared absorption spectra of amorphous and crystalline water ice in the 10-50 K and 10-140 K temperature range, respectively, and conducted a systematic experimental study to investigate the amorphization of crystalline water ice via ionizing radiation irradiation at doses of up to 160 pm 30 eV per molecule. We found that crystalline water ice can be converted only partially to amorphous ice by electron irradiation. The experiments showed that a fraction of the 1.65 mum band, which is characteristic for crystalline water ice, survived the irradiation, to a degree that strongly depends on the temperature. Quantitative kinetic fits of the temporal evolution of the 1.65 mum band clearly demonstrate that there is a balance between thermal recrystallization and irradiation-induced amorphization, with thermal recrystallizaton dominant at higher temperatures. Our experiments show the amorphization at 40K was incomplete, in contradiction to Mastrapa and Browns conclusion (Icarus 2006, 183, 207.). At 50 K, the recrystallization due to thermal effects is strong, and most of the crystalline ice survived. Temperatures of most icy objects in the Solar System, including Jovian satellites, Saturnian satellites (including Titan), and Kuiper Belt Objects, are equal to or above 50 K; this explains why water ice detected on those objects is mostly crystalline.
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Our knowledge about the physical processes determining the activity of comets were mainly influenced by several extremely successful space missions, the predictions of theoretical models and the results of laboratory experiments. However, novel computer models should not be treated in isolation but should be based on experimental results. Therefore, a new experimental setup was constructed to investigate the temperature dependent sublimation properties of hexagonal water ice and the gas diffusion through a dry dust layer covering the ice surface. We show that this experimental setup is capable to reproduce known gas production rates of pure hexagonal water ice. The reduction of the gas production rate due to an additional dust layer on top of the ice surface was measured and compared to the results of another experimental setup in which the gas diffusion through dust layers at room temperature was investigated. We found that the relative permeability of the dust layer is inversely proportional to its thickness, which is also predicted by theoretical models. However, the measured absolute weakening of the gas flow was smaller than predicted by models. This lack of correspondence between model and experiment may be caused by an ill-determination of the boundary condition in the theoretical models, which further demonstrates the necessity of laboratory investigations. Furthermore, the impedance of the dust layer to the ice evaporation was found to be similar to the impedance at room temperature, which means that the temperature profile of the dust layer is not influencing the reduction of the gas production. Finally, we present the results of an extended investigation of the sublimation coefficient, which is an important factor for the description of the sublimation rate of water ice and, thus, an important value for thermophysical modeling of icy bodies in the solar system.
This brief review will discuss the current knowledge on the origin and evolution of the nitrogen atmospheres of the icy bodies in the solar system, particularly of Titan, Triton and Pluto. An important tool to analyse and understand the origin and evolution of these atmospheres can be found in the different isotopic signatures of their atmospheric constituents. The $^{14}$N/$^{15}$N ratio of the N$_2$-dominated atmospheres of these bodies serve as a footprint of the building blocks from which Titan, Triton and Pluto originated and of the diverse fractionation processes that shaped these atmospheres over their entire evolution. Together with other measured isotopic and elemental ratios such as $^{12}$C/$^{13}$C or Ar/N these atmospheres can give important insights into the history of the icy bodies in the solar system, the diverse processes that affect their N$_2$-dominated atmospheres, and the therewith connected solar activity evolution. Titans gaseous envelope most likely originated from ammonia ices with possible contributions from refractory organics. Its isotopic signatures can yet be seen in the - compared to Earth - comparatively heavy $^{14}$N/$^{15}$N ratio of 167.7, even though this value slightly evolved over its history due to atmospheric escape and photodissociation of N$_2$. The origin and evolution of Plutos and Tritons tenuous nitrogen atmospheres remain unclear, even though it might be likely that their atmospheres originated from the protosolar nebula or from comets. An in-situ space mission to Triton such as the recently proposed Trident mission, and/or to the ice giants would be a crucial cornerstone for a better understanding of the origin and evolution of the icy bodies in the outer solar system and their atmospheres in general.
Over the last eight years, the Visual and Infrared Mapping Spectrometer (VIMS) aboard the Cassini orbiter has returned hyperspectral images in the 0.35-5.1 micron range of the icy satellites and rings of Saturn. These very different objects show significant variations in surface composition, roughness and regolith grain size as a result of their evolutionary histories, endogenic processes and interactions with exogenic particles. The distributions of surface water ice and chromophores, i.e. organic and non-icy materials, across the saturnian system, are traced using specific spectral indicators (spectral slopes and absorption band depths) obtained from rings mosaics and disk-integrated satellites observations by VIMS.
Water content and the internal evolution of terrestrial planets and icy bodies are closely linked. The distribution of water in planetary systems is controlled by the temperature structure in the protoplanetary disk and dynamics and migration of planetesimals and planetary embryos. This results in the formation of planetesimals and planetary embryos with a great variety of compositions, water contents and degrees of oxidation. The internal evolution and especially the formation time of planetesimals relative to the timescale of radiogenic heating by short-lived 26Al decay may govern the amount of hydrous silicates and leftover rock-ice mixtures available in the late stages of their evolution. In turn, water content may affect the early internal evolution of the planetesimals and in particular metal-silicate separation processes. Moreover, water content may contribute to an increase of oxygen fugacity and thus affect the concentrations of siderophile elements within the silicate reservoirs of Solar System objects. Finally, the water content strongly influences the differentiation rate of the icy moons, controls their internal evolution and governs the alteration processes occurring in their deep interiors.
Identifying the source of Earths water is central to understanding the origins of life-fostering environments and to assessing the prevalence of such environments in space. Water throughout the solar system exhibits deuterium-to-hydrogen enrichments, a fossil relic of low-temperature, ion-derived chemistry within either (i) the parent molecular cloud or (ii) the solar nebula protoplanetary disk. Utilizing a comprehensive treatment of disk ionization, we find that ion-driven deuterium pathways are inefficient, curtailing the disks deuterated water formation and its viability as the sole source for the solar systems water. This finding implies that if the solar systems formation was typical, abundant interstellar ices are available to all nascent planetary systems.
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