Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userGeneralization of Eight Methods for Determining R in the Ideal Gas Law
97
0
0.0
(
0
)
Authors
Donald B. Macnaughton
Ask ChatGPT about the research
No Arabic abstract
The ideal gas law of physics and chemistry says that PV = nRT. This law is a statement of the relationship between four variables (P, V, n, and T) that reflect properties of a quantity of gas in a container. The law enables us to make accurate predictions of the value of any one of the four variables from the values of the other three. The symbol R (called the molar gas constant) is the sole parameter or constant of the law. R stands for a fixed number that has been shown through experiments to equal approximately 8.314472. Eight methods are available to analyze the data from a relevant experiment to determine the value of R. These methods are specific instances of eight general methods that scientists use to determine the value(s) of the parameter(s) of a model equation of a relationship between variables. Parameter estimation is one step in the study of a relationship between variables.
rate research
Read More
We study the popular centrality measure known as effective conductance or in some circles as information centrality. This is an important notion of centrality for undirected networks, with many applications, e.g., for random walks, electrical resistor networks, epidemic spreading, etc. In this paper, we first reinterpret this measure in terms of modulus (energy) of families of walks on the network. This modulus centrality measure coincides with the effective conductance measure on simple undirected networks, and extends it to much more general situations, e.g., directed networks as well. Secondly, we study a variation of this modulus approach in the egocentric network paradigm. Egonetworks are networks formed around a focal node (ego) with a specific order of neighborhoods. We propose efficient analytical and approximate methods for computing these measures on both undirected and directed networks. Finally, we describe a simple method inspired by the modulus point-of-view, called shell degree, which proved to be a useful tool for network science.
Many time series produced by complex systems are empirically found to follow power-law distributions with different exponents $alpha$. By permuting the independently drawn samples from a power-law distribution, we present non-trivial bounds on the memory strength (1st-order autocorrelation) as a function of $alpha$, which are markedly different from the ordinary $pm 1$ bounds for Gaussian or uniform distributions. When $1 < alpha leq 3$, as $alpha$ grows bigger, the upper bound increases from 0 to +1 while the lower bound remains 0; when $alpha > 3$, the upper bound remains +1 while the lower bound descends below 0. Theoretical bounds agree well with numerical simulations. Based on the posts on Twitter, ratings of MovieLens, calling records of the mobile operator Orange, and browsing behavior of Taobao, we find that empirical power-law distributed data produced by human activities obey such constraints. The present findings explain some observed constraints in bursty time series and scale-free networks, and challenge the validity of measures like autocorrelation and assortativity coefficient in heterogeneous systems.
The geometric-mean method is often used to estimate the spatial resolution of a position-sensitive detector probed by tracks. It calculates the resolution solely from measured track data without using a detailed tracking simulation and without considering multiple Coulomb scattering effects. Two separate linear track fits are performed on the same data, one excluding and the other including the hit from the probed detector. The geometric mean of the widths of the corresponding exclusive and inclusive residual distributions for the probed detector is then taken as a measure of the intrinsic spatial resolution of the probed detector: $sigma=sqrt{sigma_{ex}cdotsigma_{in}}$. The validity of this method is examined for a range of resolutions with a stand-alone Geant4 Monte Carlo simulation that specifically takes multiple Coulomb scattering in the tracking detector materials into account. Using simulated as well as actual tracking data from a representative beam test scenario, we find that the geometric-mean method gives systematically inaccurate spatial resolution results. Good resolutions are estimated as poor and vice versa. The more the resolutions of reference detectors and probed detector differ, the larger the systematic bias. An attempt to correct this inaccuracy by statistically subtracting multiple-scattering effects from geometric-mean results leads to resolutions that are typically too optimistic by 10-50%. This supports an earlier critique of this method based on simulation studies that did not take multiple scattering into account.
We present an unbiased and robust analysis method for power-law blinking statistics in the photoluminescence of single nano-emitters, allowing us to extract both the bright- and dark-state power-law exponents from the emitters intensity autocorrelation functions. As opposed to the widely-used threshold method, our technique therefore does not require discriminating the emission levels of bright and dark states in the experimental intensity timetraces. We rely on the simultaneous recording of 450 emission timetraces of single CdSe/CdS core/shell quantum dots at a frame rate of 250 Hz with single photon sensitivity. Under these conditions, our approach can determine ON and OFF power-law exponents with a precision of 3% from a comparison to numerical simulations, even for shot-noise-dominated emission signals with an average intensity below 1 photon per frame and per quantum dot. These capabilities pave the way for the unbiased, threshold-free determination of blinking power-law exponents at the micro-second timescale.
This paper develops an analytical and rigorous formulation of the maximum entropy generation principle. The result is suggested as the Fourth Law of Thermodynamics.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
