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Spin-lattice relaxation rate $T_1^{-1}$ of $^1$H-NMR has been measured in (CH$_3$)$_2$CHNH$_3$Cu(Cl$_x$Br$_{1-x}$)$_3$ with $x=0.88$, which has been reported to be gapped system with singlet ground state from the previous macroscopic magnetization and specific heat measurements, in order to investigate the bond randomness effect microscopically in the gapped composite Haldane system (CH$_3$)$_2$CHNH$_3$CuCl$_3$. It was found that the spin-lattice relaxation rate $T_1^{-1}$ in the present system includes both fast and slow relaxation parts indicative of the gapless magnetic ground state and the gapped singlet ground state, respectively. We discuss the obtained results with the previous macroscopic magnetization and specific heat measurements together with the microscopic $mu$SR experiments.
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Raman spectroscopy is used to study magnetic excitations in the quasi one dimensional $S=1/2$ quantum spin systems Cu(Qnx)(Cl$_{1-x}$Br$_x$)$_2$. The low energy spectrum is found to be dominated by a two-magnon continuum as expected from the numerical calculations for the Heisenberg spin ladder model. The continuum shifts to higher energies as more Br is introduced. The cutoff of the scattering increases faster than the onset indicating that the increase of exchange constant along the leg is the main effect on the magnetic properties. The upper and lower continuum thresholds are measured as a function of Br content across the entire range and compared to estimates based on previous bulk studies. We observe small systematic deviations that are discussed.
The spin-lattice relaxation rate $T_1^{-1}$ of $^1$H-NMR has been measured in (CH$_3$)$_2$CHNH$_3$Cu(Cl$_x$Br$_{1-x}$)$_3$ with $x=0$ and 0.35, in order to investigate the microscopic magnetism of systems. Previous macroscopic magnetization and specific heat measurements suggested that these two exist in a singlet-dimer phase. The temperature dependence of $T_1^{-1}$ in an $x=0$ system decreased exponentially toward zero, indicating microscopic evidence of the gapped singlet ground state, which is consistent with the macroscopic experiments. At the same time, in the $x=0.35$ system, $T_1^{-1}$ showed a sharp peak structure at around 7.5 K though no splitting of $^1$H-NMR spectra indicative of the magnetic ordering was observed. We discuss the observed sharp peak structure in the $x=0.35$ system with the soft mode toward the exotic magnetic ground state suggested by the recent $mu$SR experiments.
We report the results of ac and dc magnetization (M) and heat-capacity (C) measurements on the solid solution, Sr$_3$Cu$_{1-x}$Zn$_x$IrO$_6$. While the Zn end member is known to form in a rhombohedral pseudo one-dimensional K$_4$CdCl$_6$ structure with an antiferromagnetic ordering temperature of (T$_N$ =) 19 K, the Cu end member has been reported to form in a monoclinically distorted form with a Curie temperature of (T$_C$ =) 19 K. The magnetism of the Zn compound is found to be robust to synthetic conditions and is broadly consistent with the behavior known in the literature. However, we find a lower magnetic ordering temperature (T$_o$) for our Cu compound (~ 13 K), thereby suggesting that T$_o$ is sensitive to synthetic conditions. The Cu sample appears to be in a spin-glass-like state at low temperatures, judged by a frequency dependence of ac magnetic susceptibility and a broadening of the C anomaly at the onset of magnetic ordering, in sharp contrast to earlier proposals. Small applications of magnetic field, however, drive this system to ferromagnetism as inferred from the M data. Small substitutions for Cu/Zn (x = 0.75 or 0.25) significantly depress magnetic ordering; in other words, T$_o$ varies non-monotonically with x (T$_o$ ~ 6, 3 and 4 K for x = 0.25, 0.5, and 0.67 respectively). The plot of inverse susceptibility versus temperature is non-linear in the paramagnetic state as if correlations within (or among) the magnetic chains continuously vary with temperature. The results establish
Density-functional calculations of lattice dynamics and high-resolution synchrotron powder diffraction uncover antiferroelectric distortion in the kagome francisite Cu$_3$Bi(SeO$_3$)$_2$O$_2$Cl below 115K. Its Br-containing analogue is stable in the room-temperature crystal structure down to at least 10K, although the Br compound is on the verge of a similar antiferroelectric instability and reveals local displacements of Cu and Br atoms. The I-containing compound is stable in its room-temperature structure according to density-functional calculations. We show that the distortion involves cooperative displacements of Cu and Cl atoms, and originates from the optimization of interatomic distances for weakly bonded halogen atoms. The distortion introduces a tangible deformation of the kagome spin lattice and may be responsible for the reduced net magnetization of the Cl compound compared to the Br one. The polar structure of Cu$_3$Bi(SeO$_3$)$_2$O$_2$Cl is only slightly higher in energy than the non-polar antiferroelectric structure, but no convincing evidence of its formation could be obtained.
The spin-1/2 stacked triangular antiferromagnet CsCu$_{1-x}$Co$_x$Cl$_3$ with $0.015<x<0.032$ undergoes two phase transitions at zero field. The low-temperature phase is produced by the small amount of Co$^{2+}$ doping. In order to investigate the magnetic structures of the two ordered phases, the neutron elastic scattering experiments have been carried out for the sample with $xapprox 0.03$. It is found that the intermediate phase is identical to the ordered phase of CsCuCl$_3$, and that the low-temperature phase is an oblique triangular antiferromagnetic phase in which the spins form a triangular structure in a plane tilted from the basal plane. The tilting angle which is 42$^{circ}$ at $T=1.6$ K decreases with increasing temperature, and becomes zero at $T_{rm N2} =7.2$ K. An off-diagonal exchange term is proposed as the origin of the oblique phase.
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