In this paper, we enumerate prime graphs with respect to the Cartesian multiplication of graphs. We use the unique factorization of a connected graph into the product of prime graphs given by Sabidussi to find explicit formulas for labeled and unlabeled prime graphs. In the case of species, we construct the exponential composition of species based on the arithmetic product of species of Maia and Mendez and the quotient species, and express the species of connected graphs as the exponential composition of the species of prime graphs.
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