This study aims to construct a mathematical model to calculate the form factor of Palestine Oak Maquis grown on the eastern versants of coastal mountains. The form factor model can help foresters to precisely estimate the volume of tree and forest stands. In the year 2014, 129 oak shoots of various ages and sizes, located in natural stands of different densities and site qualities covering all conditions of region grown on, were felled. Diameters at different heights of the felled shoots were measured; shoots volumes and volumes of equivalent cylinders were calculated, and consequently the values of shoot form factor were computed. The dataset was randomly split into two parts, 70% (90 shoots) of the data for constructing form factor model and 30% (39 trees) for model validation. Several form factor models were developed using the non-linear regression equations in the statistical program SPSS. Best fit to the data was selected and value of the coefficient of determination adjusted (R²adj) was about 0.77. The model has been validated using several statistical methods, the relative bias of the best model ( e%) was ca. -3.6 %, while the value of model accuracy ) % x m ) was 15%. In order to obtain lower value of model relative bias and higher value of accuracy, it’s recommended to use a larger database comprising all distribution areas of oak Maquis in Syria.