The possibility of using tuff and modified Jordanian naturalzeolite to remove the iron ions, a model component of heavy metals in underground water, off aqueous solution were studied. Bench-scale process was used to remove the iron ions off standard solutions and real under ground water. Different parameters affected the ion exchange have been investigated, such as concentration, modifier type and PH. Zeolite characterizations weredetermined as XRD, XRF, BET, TGA, andFTIRmethods.We found that the modified zeolite with sodium chloride had more effect than other salts and the iron ions exchange efficiency depends on concentration.Zeolite efficiency was affected by PH value. Time of sorption equilibrium achieved within 250 min. The results agree with Langmuir model.