The work could be considered as a continuous study of (XRL) X – ray luminescence - spectra of pure, and mixed Zno different AL ions, In these films and other crystals powders prepared by new developed te chnology. We studied the pure and ZnO thin films. mixed with an AL - ions in the fielol (200-700)nm ,at different weig hrs (5,10,15,20)wt% prepared by thermal evaporation. This way is cheep and a simple technology. Our study showed different spectra peaks at the wavelengths(335,410,521)nm anol (t=20ns)produced, at different peaks intensities of the prepared thin films, compared with those jure and mixeol ZnO ones, spray pyrolysis. Thin films technology, have many wide scientific application, in the medical field, Lazer technology, Luminscence counters, and at the solar cells fields