This paper presents our work in WMT 2021 Quality Estimation (QE) Shared Task. We participated in all of the three sub-tasks, including Sentence-Level Direct Assessment (DA) task, Word and Sentence-Level Post-editing Effort task and Critical Error Detection task, in all language pairs. Our systems employ the framework of Predictor-Estimator, concretely with a pre-trained XLM-Roberta as Predictor and task-specific classifier or regressor as Estimator. For all tasks, we improve our systems by incorporating post-edit sentence or additional high-quality translation sentence in the way of multitask learning or encoding it with predictors directly. Moreover, in zero-shot setting, our data augmentation strategy based on Monte-Carlo Dropout brings up significant improvement on DA sub-task. Notably, our submissions achieve remarkable results over all tasks.