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Generalization of Classical Statistical Mechanics to Quantum Mechanics and Stable Property of Condensed Matter

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 Added by Y. C. Huang
 Publication date 2005
  fields Physics
and research's language is English




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Classical statistical average values are generally generalized to average values of quantum mechanics, it is discovered that quantum mechanics is direct generalization of classical statistical mechanics, and we generally deduce both a new general continuous eigenvalue equation and a general discrete eigenvalue equation in quantum mechanics, and discover that a eigenvalue of quantum mechanics is just an extreme value of an operator in possibility distribution, the eigenvalue f is just classical observable quantity. A general classical statistical uncertain relation is further given, the general classical statistical uncertain relation is generally generalized to quantum uncertainty principle, the two lost conditions in classical uncertain relation and quantum uncertainty principle, respectively, are found. We generally expound the relations among uncertainty principle, singularity and condensed matter stability, discover that quantum uncertainty principle prevents from the appearance of singularity of the electromagnetic potential between nucleus and electrons, and give the failure conditions of quantum uncertainty principle. Finally, we discover that the classical limit of quantum mechanics is classical statistical mechanics, the classical statistical mechanics may further be degenerated to classical mechanics, and we discover that only saying that the classical limit of quantum mechanics is classical mechanics is mistake. As application examples, we deduce both Shrodinger equation and state superposition principle, deduce that there exist decoherent factor from a general mathematical representation of state superposition principle, and the consistent difficulty between statistical interpretation of quantum mechanics and determinant property of classical mechanics is overcome.



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We show that the main difference between classical and quantum systems can be understood in terms of information entropy. Classical systems can be considered the ones where the internal dynamics can be known with arbitrary precision while quantum systems can be considered the ones where the internal dynamics cannot be accessed at all. As information entropy can be used to characterize how much the state of the whole system identifies the state of its parts, classical systems can have arbitrarily small information entropy while quantum systems cannot. This provides insights that allow us to understand the analogies and differences between the two theories.
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Simple theorems relating a quantum mechanical system to the corresponding classical one at equilibrium and connecting the quantum eigenvalues to the frequencies of normal modes oscillations are presented. Corresponding to each quantum eigenfunction, a ` classical eigenfunction is associated. Those belonging to `elementary excitations play an important role.
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