An arbitrary polarization state of a single-mode biphoton is considered. The operationalistic criterion is formulated for the orthogonality og these states. It can be used to separate a biphoton with an arbitrary degree of polarization from a set of biphotons orthogonal to it. This is necessary fro the implementation of quantum cryptography protocol based on three-level systems. The experimental test of this criterion amounts to the observation of the anticorrelation effect for a biphoton with an arbitraty polarization state.
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