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A possible explanation of the phase diagram of cuprate superconductors

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 Added by Tian De Cao
 Publication date 2007
  fields Physics
and research's language is English




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A d-p pairing curve that is consistent with the pseudogap curve observed in experiments is found on a d-p model on phonon mechanism. On the discovery we suggest that there are two pseudogaps associated with the nearly localized d-p pairs and nearly free p-p pairs. The p-p pairs look like bosons and are responsible for superconductivities.



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Taking the spin-fermion model as the starting point for describing the cuprate superconductors, we obtain an effective nonlinear sigma-field hamiltonian, which takes into account the effect of doping in the system. We obtain an expression for the spin-wave velocity as a function of the chemical potential. For appropriate values of the parameters we determine the antiferromagnetic phase diagram for the YBa$_2$Cu$_3$O$_{6+x}$ compound as a function of the dopant concentration in good agreement with the experimental data. Furthermore, our approach provides a unified description for the phase diagrams of the hole-doped and the electron doped compounds, which is consistent with the remarkable similarity between the phase diagrams of these compounds, since we have obtained the suppression of the antiferromagnetic phase as the modulus of the chemical potential increases. The aforementioned result then follows by considering positive values of the chemical potential related to the addition of holes to the system, while negative values correspond to the addition of electrons.
Starting from a spin-fermion model for the cuprate superconductors, we obtain an effective interaction for the charge carriers by integrating out the spin degrees of freedom. Our model predicts a quantum critical point for the superconducting interaction coupling, which sets up a threshold for the onset of superconductivity in the system. We show that the physical value of this coupling is below this threshold, thus explaining why there is no superconducting phase for the undoped system. Then, by including doping, we find a dome-shaped dependence of the critical temperature as charge carriers are added to the system, in agreement with the experimental phase diagram. The superconducting critical temperature is calculated without adjusting any free parameter and yields, at optimal doping $ T_c sim $ 45 K, which is comparable to the experimental data.
Universal scaling laws can guide the understanding of new phenomena, and for cuprate high-temperature superconductivity such an early influential relation showed that the critical temperature of superconductivity ($T_c$) correlates with the density of the superfluid measured at low temperatures. This famous Uemura relation has been inspiring the community ever since. Here we show that the charge content of the bonding orbitals of copper and oxygen in the ubiquitous CuO$_2$ plane, accessible with nuclear magnetic resonance (NMR), is tied to the Uemura scaling. This charge distribution between copper and oxygen varies between cuprate families and with doping, and it allows us to draw a new phase diagram that has different families sorted with respect to their maximum $T_c$. Moreover, it also shows that $T_c$ could be raised substantially if we were able to synthesize materials in which more oxygen charge is transferred to the approximately half filled copper orbital.
115 - W. Sacks , T. Cren , D. Roditchev 2006
We previously introduced [T. Cren et al., Europhys. Lett. 52, 203 (2000)] an energy-dependant gap function, $Delta(E)$, that fits the unusual shape of the quasiparticle (QP) spectrum for both BiSrCaCuO and YBaCuO. A simple anti-resonance in $Delta(E)$ accounts for the pronounced QP peaks in the density of states, at an energy $Delta_p$, and the dip feature at a higher energy, $E_{dip}$. Here we go a step further : our gap function is consistent with the ($T, p$) phase diagram, where $p$ is the carrier density. For large QP energies ($E >> Delta_p$), the total spectral gap is $Delta(E) simeq Delta_p + Delta_phi$, where $Delta_phi$ is tied to the condensation energy. From the available data, a simple $p$-dependance of $Delta_p$ and $Delta_phi$ is found, in particular $Delta_phi(p) simeq 2.3 k_B T_c(p)$. These two distinct energy scales of the superconducting state are interpreted by comparing with the normal and pseudogap states. The various forms of the QP density of states, as well as the spectral function $A(k,E)$, are discussed.
We propose that Resistivity Curvature Mapping (RCM) based on the in-plane resistivity data is a useful way to objectively draw an electronic phase diagrams of high-T_c cuprates, where various crossovers are important. In particular, the pseudogap crossover line can be conveniently determined by RCM. We show experimental phase diagrams obtained by RCM for Bi_{2}Sr_{2-z}La_{z}CuO_{6+delta}, La_{2-x}Sr_{x}CuO_{4}, and YBa_{2}Cu_{3}O_{y}, and demonstrate the universal nature of the pseudogap crossover. Intriguingly, the electronic crossover near optimum doping depicted by RCM appears to occur rather abruptly, suggesting that the quantum critical regime, if exists, must be very narrow.
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