Measurement of the hyperfine structure of the S1/2-D5/2 transition in 43Ca+

The hyperfine structure of the S1/2-D5/2 quadrupole transition at 729 nm in 43Ca+ has been investigated by laser spectroscopy using a single trapped 43Ca+ ion. We determine the hyperfine structure constants of the metastable level as A=-3.8931(2) MHz and B=-4.241(4) MHz. The isotope shift of the transition with respect to 40Ca+ was measured to be 4134.713(5) MHz. We demonstrate the existence of transitions that become independent of the first-order Zeeman shift at non-zero low magnetic fields. These transitions might be better suited for building a frequency standard than the well-known clock transitions between m=0 levels at zero magnetic field.