No Arabic abstract
In this paper we prove the following: (1) The basic error of time-dependent perturbation theory is using the sum of first finite order of perturbed solutions to substitute the exact solution in the divergent interval of the series for calculating the transition probability. In addition quantum mechanics neglects the influence of the normality condition in the continuous case. In both cases Fermi golden rule is not a mathematically reasonable deductive inference from the Schrodinger equation. (2) The transition probability per unit time deduced from the exact solution of the Schrodinger equation is zero, which cannot be used to describe the transition processes.
By constructing the commutative operators chain, we derive the integrable conditions for solving the eigenfunctions of Dirac equation and Schrodinger equation. These commutative relations correspond to the intrinsic symmetry of the physical system, which are equivalent to the original partial differential equation can be solved by separation of variables. Detailed calculation shows that, only a few cases can be completely solved by separation of variables. In general cases, we have to solve the Dirac equation and Schrodinger equation by effective perturbation or approximation methods, especially in the cases including nonlinear potential or self interactive potentials.
We propose that the Schrodinger equation results from applying the classical wave equation to describe the physical system in which subatomic particles play random motion, thereby leading to quantum mechanics. The physical reality described by the wave function is subatomic particle moving randomly. Therefore, the characteristics of quantum mechanics have a dual nature, one of them is the deterministic nature carried on from classical physics, and the other is the probabilistic nature coined by particles random motion. Based on this model, almost all of open questions in quantum mechanics can be explained consistently, which include the particle-wave duality, the principle of quantum superposition, the interference pattern of double-slit experiments, and the boundary between classical world and quantum world.
This paper proposes an effective diffusion equation method to analyze nuclear magnetic resonance (NMR) relaxation. NMR relaxation is a spin system recovery process, where the evolution of the spin system is affected by the random field due to Hamiltonians, such as dipolar couplings. The evolution of magnetization can be treated as a random walk in phase space described either by a normal or fractional phase diffusion equation. Based on these phase diffusion equations, the NMR relaxation rates and equations can be obtained, exemplified in the analysis of relaxations affected by an arbitrary random field, and by dipolar coupling for both like and unlike spins. The obtained theoretical results are consistent with the reported results in the literature. Additionally, the anomalous relaxation expression obtained from the Mittag-Leffler function based time correlation function can successfully fit the previously reported 13C T1 NMR experimental data of polyisobutylene (PIB) in the blend of PIB and head-to-head poly(propylene) (hhPP). Furthermore, the proposed phase diffusion approach provides an intuitive way to interpret NMR relaxation, particularly for the fractional NMR relaxation, which is still a challenge to explain by the available theoretical methods. The paper provides additional insights into NMR and magnetic resonance imaging (MRI) relaxation experiments.
Lagrangian formulation of quantum mechanical Schrodinger equation is developed in general and illustrated in the eigenbasis of the Hamiltonian and in the coordinate representation. The Lagrangian formulation of physically plausible quantum system results in a well defined second order equation on a real vector space. The Klein-Gordon equation for a real field is shown to be the Lagrangian form of the corresponding Schrodinger equation.
A covariant non-local extention if the stationary Schrodinger equation is presented and its solution in terms of Heisenbergss matrix quantum mechanics is proposed. For the special case of the Riesz fractional derivative, the calculation of corresponding matrix elements for the non-local kinetic energy term is performed fully analytically in the harmonic oscillator basis and leads to a new interpretation of non local operators in terms of generalized Glauber states. As a first application, for the fractional harmonic oscillator the potential energy matrix elements are calculated and the and the corresponding Schrodinger equation is diagonalized. For the special case of invariance of the non-local wave equation under Fourier-transforms a new symmetry is deduced, which may be interpreted as an extension of the standard parity-symmetry.