The systematics of Statistical Model parameters extracted from heavy-ion collisions at lower energies are exploited to extrapolate in the LHC regime. Predictions of various particle ratios are presented and particle production in central Pb-Pb collisions at LHC is discussed in the context of the Statistical Model. The sensitivity of several ratios on the temperature and the baryon chemical potential is studied in detail, and some of them, which are particularly appropriate to determine the chemical freeze-out point experimentally, are indicated. The impact of feed-down contributions from resonances, especially to light hadrons, is illustrated.
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