We present the exact O(alpha) correction to the process e+ e- -> f f-bar + gamma, f neq e, for ISR oplus FSR at and beyond LEP2 energies. We give explicit formulas for the completely differential cross section. As an important application, we compute the size of the respective sub-leading corrections of O(alpha L) to the f f-bar cross section, where L is the respective big logarithm in the renormalization group sense so that it is identifiable as L = ln |s|/m_e^2 when s is the squared e+e- cms energy. Comparisons are made with the available literature. We show explicitly that our results have the correct infrared limit, as a cross-check. Some comments are made about the implementation of our results in the framework of the Monte Carlo event generator KK MC.
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