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X-ray Resonant Magnetic Scattering : Polarisation Dependence in the non-spherical case

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 Added by Alessandro Mirone
 Publication date 2006
  fields Physics
and research's language is English




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We develop a simple tensorial contraction method to obtain analytical formula for X-ray resonant magnetic scattering. We apply the method considering first electric dipole-dipole and electric quadrupole-quadrupole scattering in the isolated atom approximation and compare the results with previous works. Then we apply the method to derive phenomenological original formulas which account also for non-spherical systems and for dipole-quadrupole mixing.

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Simple analytical formulae, directly relating the experimental geometry and sample orientation to the measured R(M)XS scattered intensity are very useful to design experiments and analyse data. Such formulae can be obtained by the contraction of an expression containing the polarisations and crystal field tensors, and where the magnetisation vector acts as a rotation derivativecite{mirone}. The result of a contraction contains a scalar product of (rotated) polarisation vectors and the crystal field axis. The contraction rules give rise to combinatorial algorithms which can be efficiently treated by computers. In this work we provide and discuss a concise Mathematica code along with a few example applications to non-centrosymmetric magnetic systems.
We report the direct observation of slow fluctuations of helical antiferromagnetic domains in an ultra-thin holmium film using coherent resonant magnetic x-ray scattering. We observe a gradual increase of the fluctuations in the speckle pattern with increasing temperature, while at the same time a static contribution to the speckle pattern remains. This finding indicates that domain-wall fluctuations occur over a large range of time scales. We ascribe this non-ergodic behavior to the strong dependence of the fluctuation rate on the local thickness of the film.
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Element-specific x-ray resonant magnetic scattering investigations were performed to determine the magnetic structure of Eu in EuRh2As2. In the temperature range from 46 K down to 6 K, an incommensurate antiferromagnetic (ICM)structure with a temperature dependent propagation vector (0 0 0.9) coexists with a commensurate antiferromagnetic (CM) structure. Angular-dependent measurements of the magnetic intensity indicate that the magnetic moments lie in the tetragonal basal plane and are ferromagnetically aligned within the a-b plane for both magnetic structures. The ICM structure is a spiral-like magnetic structure with a turn angle of 162 deg between adjacent Eu planes. In the CM structure, this angle is 180 deg. These results are consistent with band-structure calculations which indicate a strong sensitivity of the magnetic configuration on the Eu valence.
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Comprehensive x-ray scattering studies, including resonant scattering at Mn L-edge, Tb L- and M-edges, were performed on single crystals of TbMn2O5. X-ray intensities were observed at a forbidden Bragg position in the ferroelectric phases, in addition to the lattice and the magnetic modulation peaks. Temperature dependences of their intensities and the relation between the modulation wave vectors provide direct evidences of exchange striction induced ferroelectricity. Resonant x-ray scattering results demonstrate the presence of multiple magnetic orders by exhibiting their different temperature dependences. The commensurate-to-incommensurate phase transition around 24 K is attributed to discommensuration through phase slipping of the magnetic orders in spin frustrated geometries. We proposed that the low temperature incommensurate phase consists of the commensurate magnetic domains separated by anti-phase domain walls which reduce spontaneous polarizations abruptly at the transition.
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