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Register a new userMass enhancement, correlations, and strong coupling superconductivity in the beta-pyrochlore KOs2O6
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Added by
Markus Br\\\"uhwiler
Publication date
2006
fields
Physics
and research's language is
English
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To assess electron correlation and electron-phonon coupling in the recently discovered beta-pyrochlores KOs2O6 and RbOs2O6, we have performed specific heat measurements in magnetic fields up to 14 T. We present data from high quality single crystalline KOs2O6, showing that KOs2O6 is a strong coupling superconductor with a coupling parameter lambda_ep approx 1.0 to 1.6 (RbOs2O6: lambda_ep approx 1). The estimated Sommerfeld coefficient of KOs2O6, gamma=76 to 110 mJ/(mol K^2), is twice that of RbOs2O6 [gamma=44 mJ/(mol K^2)]. Using strong-coupling corrections, we extract useful thermodynamic parameters of KOs2O6. Quantifying lambda_ep allows us to determine the mass enhancement over the calculated band electronic density of states. A significant contribution in addition to the electron-phonon term of lambda_c=1.7 to 4.3 is deduced. In an effort to understand the origin of the enhancement mechanism, we also investigate an unusual energetically low-lying phonon. There are three phonon modes per RbOs2O6, suggestive of the phonon source being the rattling motion of the alkali ion. This dynamic instability of the alkali ions causes large scattering of the charge carriers which shows up in an unusual temperature dependence of the electrical resistivity.
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To elucidate the nature of the superconducting ground state of the geometrically frustrated pyrochlore KOs2O6 (Tc=9.6K), the thermal conductivity was measured down to low temperatures (~Tc/100). We found that the quasiparticle mean free path is strikingly enhanced below a transition at Tp=7.5K, indicating enormous electron inelastic scattering in the normal state. In a magnetic field the conduction at T ->0K is nearly constant up to ~0.4Hc2, in contrast with the rapid growth expected for superconductors with an anisotropic gap. This unambiguously indicates a fully gapped superconductivity, in contrast to the previous studies. These results highlight that KOs2O6 is unique among superconductors with strong electron correlations.
Superconducting and normal-state properties of the beta-pyrochlore oxide KOs2O6 are studied by means of thermodynamic and transport measurements. It is shown that the superconductivity is of conventional s-wave type and lies in the extremely strong-coupling regime. Specific heat and resistivity measurements reveal that there are characteristic low-energy phonons that give rise to unusual scattering of carriers due to strong electron-phonon interactions. The entity of the low-energy phonons is ascribed to the heavy rattling of the K ion confined in an oversized cage made of OsO6 octahedra. It is suggested that this electron-rattler coupling mediates the Cooper pairing, resulting in the extremely strong-coupling superconductivity.
Resistivity and specific heat have been measured on a single crystalline sample of the beta-pyrochlore oxide superconductor, KOs2O6. It is found that a second peak in specific heat, which may evidence an unknown phase transition, appears around Tp ~ 7.5 K below the superconducting transition temperature Tc = 9.53 K. Applying magnetic fields up to 14 T, Tc is reduced gradually down to 7.1 K, while Tp is raised a little and becomes even higher than Tc at 14 T, which implies that the second anomaly is not associated directly with the superconductivity. It is demonstrated, however, that there is significant communication between the two anomalies, suggesting that they come from the same electrons. It is also reported that the Sommerfeld coefficient ? in KOs2O6 is possibly much larger than in other members of beta-pyrochlore oxide superconductors, RbOs2O6 (Tc = 6.3 K) and CsOs2O6 (Tc = 3.3 K).
We present a comprehensive study of the low-temperature heat capacity and thermal expansion of single crystals of the hole-doped Ba1-xKxFe2As2 series (0<x<1) and the end-members RbFe2As2 and CsFe2As2. A large increase of the Sommerfeld coefficient is observed with both decreasing band filling and isovalent substitution (K, Rb, Cs) revealing a strong enhancement of electron correlations and the possible proximity of these materials to a Mott insulator. This trend is well reproduced theoretically by our Density-Functional Theory + Slave-Spin (DFT+SS) calculations, confirming that 122-iron pnictides are effectively Hund metals, in which sizable Hunds coupling and orbital selectivity are the key ingredients for tuning correlations. We also find direct evidence for the existence of a coherence-incoherence crossover between a low-temperature heavy Fermi liquid and a highly incoherent high-temperature regime similar to heavy fermion systems. In the superconducting state, clear signatures of multiband superconductivity are observed with no evidence for nodes in the energy gaps, ruling out the existence of a doping-induced change of symmetry (from s to d-wave). We argue that the disappearance of the electron band in the range 0.4<x<1.0 is accompanied by a strong-to-weak coupling crossover and that this shallow band remains involved in the superconducting pairing, although its contribution to the normal state fades away. Differences between hole- and electron-doped BaFe2As2 series are emphasized and discussed in terms of strong pair breaking by potential scatterers beyond the Born limit.
Rattling-induced superconductivity in the {beta}-pyrochlore oxide KOs2O6 is investigated under high pressure up to 5 GPa. Resistivity measurements in a high-quality single crystal reveal a gradual decrease in the superconducting transition temperature Tc from 9.7 K at 1.0 GPa to 6.5 K at 3.5 GPa, followed by a sudden drop to 3.3 K at 3.6 GPa. Powder X-ray diffraction experiments show a structural transition from cubic to monoclinic or triclinic at a similar pressure. The sudden drop in Tc is ascribed to this structural tran-sition, by which an enhancement in Tc due to a strong electron-rattler interaction present in the low-pressure cubic phase is abrogated as the rattling of the K ion is completely suppressed or weakened in the high-pressure phase of reduced symmetry. In addition, we find two anomalies in the temperature dependence of resistivity in the low-pressure phase, which may be due to subtle changes in rattling vibration.
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