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Register a new userAtomic-scale surface demixing in a eutectic liquid BiSn alloy
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Resonant x-ray reflectivity of the surface of the liquid phase of the Bi$_{43}$Sn$_{57}$ eutectic alloy reveals atomic-scale demixing extending over three near-surface atomic layers. Due to the absence of underlying atomic lattice which typically defines adsorption in crystalline alloys, studies of adsorption in liquid alloys provide unique insight on interatomic interactions at the surface. The observed composition modulation could be accounted for quantitatively by the Defay-Prigogine and Strohl-King multilayer extensions of the single-layer Gibbs model, revealing a near-surface domination of the attractive Bi-Sn interaction over the entropy.
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A two dimensional crystalline layer is found at the surface of the liquid eutectic Au$_{82}$Si$_{18}$ alloy above its melting point $T_M=359 ^{circ}$C. Underlying this crystalline layer we find a layered structure, 6-7 atomic layers thick. This surface layer undergoes a first-order solid-solid phase transition occurring at $371 ^{circ}$C. The crystalline phase observed for T$>$371 $^{circ}$C is stable up to at least 430 $^{circ}$C. Grazing Incidence X-ray Diffraction data at T$>$371 $^{circ}$C imply lateral order comprising two coexisting phases of different oblique unit cells, in stark contrast with the single phase with a rectangular unit cell found for low-temperature crystalline phase $359 ^{circ}$C$<T<371 ^{circ}$C.
It is demonstrated, by numerical simulations of a 2D assembly of polydisperse disks, that there exists a range (plateau) of coarse graining scales for which the stress tensor field in a granular solid is nearly resolution independent, thereby enabling an `objective definition of this field. Expectedly, it is not the mere size of the the system but the (related) magnitudes of the gradients that determine the widths of the plateaus. Ensemble averaging (even over `small ensembles) extends the widths of the plateaus to sub-particle scales. The fluctuations within the ensemble are studied as well. Both the response to homogeneous forcing and to an external compressive localized load (and gravity) are studied. Implications to small solid systems and constitutive relations are briefly discussed.
We performed rheological measurements of the typical deep eutectic solvents (DESs) glyceline, ethaline, and reline in a very broad temperature and dynamic range, extending from the low-viscosity to the high-viscosity supercooled-liquid regime. We find that the mechanical compliance spectra can be well described by the random free-energy barrier hopping model, while the dielectric spectra on the same materials involve significant contributions arising from reorientational dynamics. The temperature-dependent viscosity and structural relaxation time, revealing non-Arrhenius behavior typical for glassy freezing, are compared to the ionic dc conductivity and relaxation times determined by broadband dielectric spectroscopy. For glyceline and ethaline we find essentially identical temperature dependences for all dynamic quantities. These findings point to a close coupling of the ionic and molecular translational and reorientational motions in these systems. However, for reline the ionic charge transport appears decoupled from the structural and reorientational dynamics, following a fractional Walden rule. Especially, at low temperatures the ionic conductivity in this DES is enhanced by about one decade compared to expectations based on the temperature dependence of the viscosity. The results for all three DESs can be understood without invoking a revolving-door mechanism previously considered as a possible charge-transport mechanism in DESs.
We have performed a thorough examination of the reorientational relaxation dynamics and the ionic charge transport of three typical deep eutectic solvents, ethaline, glyceline and reline by broadband dielectric spectroscopy. Our experiments cover a broad temperature range from the low-viscosity liquid down to the deeply supercooled state, allowing to investigate the significant influence of glassy freezing on the ionic charge transport in these systems. In addition, we provide evidence for a close coupling of the ionic conductivity in these materials to reorientational dipolar motions which should be considered when searching for deep eutectic solvents optimized for electrochemical applications.
We experimentally investigate the response of a sheared granular medium in a Couette geometry. The apparatus exhibits the expected stick-slip motion and we probe it in the very intermittent regime resulting from low driving. Statistical analysis of the dynamic fluctuations reveals notable regularities. We observe a possible stability property for the torque distribution, reminiscent of the stability of Gaussian independent variables. In this case, however, the variables are correlated and the distribution is skewed. Moreover, the whole dynamical intermittent regime can be described with a simple stochastic model, finding good quantitative agreement with the experimental data. Interestingly, a similar model has been previously introduced in the study of magnetic domain wall motion, a source of Barkhausen noise. Our study suggests interesting connections between different complex phenomena and reveals some unexpected features that remain to be explained.
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