No Arabic abstract
We have measured magnetic susceptibility and resistivity of Sr$_{1-x}$Y$_x$CoO$_{3-delta}$ ($x=$ 0.1, 0.15, 0.2, 0.215, 0.225, 0.25, 0.3, and 0.4), and have found that Sr$_{1-x}$Y$_x$CoO$_{3-delta}$ is a room temperature ferromagnet with a Curie temperature of 335 K in a narrow compositional range of 0.2 $leq xleq$ 0.25. This is the highest transition temperature among perovskite Co oxides. The saturation magnetization for $x=$ 0.225 is 0.25 $mu_B$/Co at 10 K, which implies that the observed ferromagnetism is a bulk effect. We attribute this ferromagnetism to a peculiar Sr/Y ordering.
SrTiO$_{3}$ undergoes a cubic-to-tetragonal phase transition at 105K. This antiferrodistortive transition is believed to be in competition with incipient ferroelectricity. Substituting strontium by isovalent calcium induces a ferroelectric order. Introducing mobile electrons to the system by chemical non-isovalent doping, on the other hand, leads to the emergence of a dilute metal with a superconducting ground state. The link between superconductivity and the other two instabilities is an open question, which gathers momentum in the context of the growing popularity of the paradigm linking unconventional superconductors and quantum critical points. We present a set of specific-heat, neutron-scattering and dielectric permittivity and polarization measurements on Sr$_{1-x}$Ca$_{x}$TiO$_{3}$ ($0<x<0.009$) and a low-temperature electric conductivity in Sr$_{0.9978}$Ca$_{0.0022}$TiO$_{3-delta}$. Calcium substitution was found to enhance the transition temperature for both anti-ferrodistortive and ferroelectric transitions. Moreover, we find that Sr$_{0.9978}$Ca$_{0.0022}$TiO$_{3-delta}$ has a superconducting ground state. The critical temperature in this rare case of a superconductor with a ferroelectric parent, is slightly lower than in SrTiO$_{3-delta}$ of comparable carrier concentration. A three-dimensional phase diagram for Sr$_{1-x}$Ca$_{x}$TiO$_{3-delta}$ tracking the three transition temperatures as a function of x and $delta$ results from this study, in which ferroelectric and superconducting ground states are not immediate neighbours.
We report room-temperature ferromagnetism in highly conducting transparent anatase Ti1-xTaxO2 (x~0.05) thin films grown by pulsed laser deposition on LaAlO3 substrates. Rutherford backscattering spectrometry (RBS), x-ray diffraction (XRD), proton induced x-ray emission (PIXE), x-ray absorption spectroscopy (XAS) and time-of-flight secondary ion mass spectrometry (TOF-SIMS) indicated negligible magnetic contaminants in the films. The presence of ferromagnetism with concomitant large carrier densities was determined by a combination of superconducting quantum interference device (SQUID) magnetometry, electrical transport measurements, soft x-ray magnetic circular dichroism (SXMCD), XAS, and optical magnetic circular dichroism (OMCD) and was supported by first-principle calculations. SXMCD and XAS measurements revealed a 90% contribution to ferromagnetism from the Ti ions and a 10% contribution from the O ions. RBS/channelling measurements show complete Ta substitution in the Ti sites though carrier activation was only 50% at 5% Ta concentration implying compensation by cationic defects. The role of Ti vacancy and Ti3+ was studied via XAS and x-ray photoemission spectroscopy (XPS) respectively. It was found that in films with strong ferromagnetism, the Ti vacancy signal was strong while Ti3+ signal was absent. We propose (in the absence of any obvious exchange mechanisms) that the localised magnetic moments, Ti vacancy sites, are ferromagnetically ordered by itinerant carriers. Cationic-defect-induced magnetism is an alternative route to ferromagnetism in wide-band-gap semiconducting oxides without any magnetic elements.
We present the electronic structure of Sr_{1-(x+y)}La_{x+y}Ti_{1-x}Cr_{x}O_{3} investigated by high-resolution photoemission spectroscopy. In the vicinity of Fermi level, it was found that the electronic structure were composed of a Cr 3d local state with the t_{2g}^{3} configuration and a Ti 3d itinerant state. The energy levels of these Cr and Ti 3d states are well interpreted by the difference of the charge-transfer energy of both ions. The spectral weight of the Cr 3d state is completely proportional to the spin concentration x irrespective of the carrier concentration y, indicating that the spin density can be controlled by x as desired. In contrast, the spectral weight of the Ti 3d state is not proportional to y, depending on the amount of Cr doping.
A detailed study of the magnetic and transport properties of Si1-xMnx (X = 0.35) films is presented. We observe the anomalous Hall effect (AHE) in these films up to room temperature. The results of the magnetic measurements and the AHE data are consistent and demonstrate the existence of long-range ferromagnetic (FM) order in the systems under study. A correlation of the AHE and the magnetic properties of Si1-xMnx (X = 0.35) films with their conductivity and substrate type is shown. A theoretical model based on the idea of a two-phase magnetic material, in which molecular clusters with localized magnetic moments are embedded in the matrix of a weak itinerant ferromagnet, is discussed. The long-range ferromagnetic order at high temperatures is mainly due to the Stoner enhancement of the exchange coupling between clusters through thermal spin fluctuations (paramagnons) in the matrix. Theoretical predictions and experimental data are in good qualitative agreement.
The crystal structure of Ca_{2-x}Sr_xRuO_4 with 0.2 < x < 1.0 has been studied by diffraction techniques and by high resolution capacitance dilatometry as a function of temperature and magnetic field. Upon cooling in zero magnetic field below about 25 K the structure shrinks along the c-direction and elongates in the a, b planes (0.2 < x < 1.0), whereas the opposite occurs upon cooling at high-field (x = 0.2 and 0.5). These findings indicate an orbital rearrangement driven by temperature and magnetic field, which accompanies the metamagnetic transition in these compounds.