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Register a new userThe two loop calculation of the disjoining pressure of a symmetric electrolyte soap film
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In this paper we consider the two-loop calculation of the disjoining pressure of a symmetric electrolytic soap film. We show that the disjoining pressure is finite when the loop expansion is resummed using a cumulant expansion and requires no short distance cut-off. The loop expansion is resummed in terms of an expansion in g=l_B/l_D where l_D is the Debye length and l_B is the Bjerrum length. We show that there there is a non-analytic contribution of order g*ln(g). We also show that the two-loop correction is greater than the one-loop term at large film thicknesses suggesting a non-perturbative correction to the one-loop result in this limit.
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The present work is trying to explain a discrepancy between experimental observations of the drainage of foam films from aqueous solutions of sodium dodecyl sulfate (SDS) and the theoretical DLVO-accomplished Reynolds model. It is shown that, due to overlap of the film adsorption layers, an adsorption component of the disjoining pressure is important for this system. The pre-exponential factor of the adsorption component was obtained by fitting the experimental drainage curves. It corresponds to a slight repulsion, which reduces not only the thinning velocity as observed experimentally but corrects also the film equilibrium thickness.
We carry out the calculation of the surface tension for a model electrolyte to first order in a cumulant expansion about a free field theory equivalent to the Debye-Huckel approximation. In contrast with previous calculations, the surface tension is calculated directly without recourse to integrating thermodynamic relations. The system considered is a monovalent electrolyte with a region at the interface, of width h, from which the ionic species are excluded. In the case where the external dielectric constant epsilon_0 is smaller than the electrolyte solutions dielectric constant epsilon we show that the calculation at this order can be fully regularized. In the case where h is taken to be zero the Onsager-Samaras limiting law for the excess surface tension of dilute electrolyte solutions is recovered, with corrections coming from a non-zero value of epsilon_0/epsilon.
We discuss instabilities of fluid films of nanoscale thickness, with a particular focus on films where the destabilising mechanism allows for linear instability, metastability, and absolute stability. Our study is motivated by nematic liquid crystal films; however we note that similar instability mechanisms, and forms of the effective disjoining pressure, appear in other contexts, such as the well-studied problem of polymeric films on two-layered substrates. The analysis is carried out within the framework of the long-wave approximation, which leads to a fourth order nonlinear partial different equation for the film thickness. Within the considered formulation, the nematic character of the film leads to an additional contribution to the disjoining pressure, changing its functional form. This effective disjoining pressure is characterised by the presence of a local maximum for non-vanishing film thickness. Such a form leads to complicated instability evolution that we study by analytical means, including application of marginal stability criteria, and by extensive numerical simulations that help us develop a better understanding of instability evolution in the nonlinear regime. This combination of analytical and computational techniques allows us to reach novel understanding of relevant instability mechanisms, and of their influence on transient and fully developed fluid film morphologies.
We use momentum transfer arguments to predict the friction factor $f$ in two-dimensional turbulent soap-film flows with rough boundaries (an analogue of three-dimensional pipe flow) as a function of Reynolds number Re and roughness $r$, considering separately the inverse energy cascade and the forward enstrophy cascade. At intermediate Re, we predict a Blasius-like friction factor scaling of $fproptotextrm{Re}^{-1/2}$ in flows dominated by the enstrophy cascade, distinct from the energy cascade scaling of $textrm{Re}^{-1/4}$. For large Re, $f sim r$ in the enstrophy-dominated case. We use conformal map techniques to perform direct numerical simulations that are in satisfactory agreement with theory, and exhibit data collapse scaling of roughness-induced criticality, previously shown to arise in the 3D pipe data of Nikuradse.
We develop a general framework for the description of instabilities on soap films using the Bjorling representation of minimal surfaces. The construction is naturally geometric and the instability has the interpretation as being specified by its amplitude and transverse gradient along any curve lying in the minimal surface. When the amplitude vanishes, the curve forms part of the boundary to a critically stable domain, while when the gradient vanishes the Jacobi field is maximal along the curve. In the latter case, we show that the Jacobi field is maximally localised if its amplitude is taken to be the lowest eigenfunction of a one-dimensional Schrodinger operator. We present examples for the helicoid, catenoid, circular helicoids and planar Enneper minimal surfaces, and emphasise that the geometric nature of the Bjorling representation allows direct connection with instabilities observed in soap films.
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