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Register a new userSurface Scaling Analysis of a Frustrated Spring-network Model for Surfactant-templated Hydrogels
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We propose and study a simplified model for the surface and bulk structures of crosslinked polymer gels, into which voids are introduced through templating by surfactant micelles. Such systems were recently studied by Atomic Force Microscopy [M. Chakrapani et al., e-print cond-mat/0112255]. The gel is represented by a frustrated, triangular network of nodes connected by springs of random equilibrium lengths. The nodes represent crosslinkers, and the springs correspond to polymer chains. The boundaries are fixed at the bottom, free at the top, and periodic in the lateral direction. Voids are introduced by deleting a proportion of the nodes and their associated springs. The model is numerically relaxed to a representative local energy minimum, resulting in an inhomogeneous, ``clumpy bulk structure. The free top surface is defined at evenly spaced points in the lateral (x) direction by the height of the topmost spring, measured from the bottom layer, h(x). Its scaling properties are studied by calculating the root-mean-square surface width and the generalized increment correlation functions C_q(x)= <|h(x_0+x)-h(x_0)|^q>. The surface is found to have a nontrivial scaling behavior on small length scales, with a crossover to scale-independent behavior on large scales. As the vacancy concentration approaches the site-percolation limit, both the crossover length and the saturation value of the surface width diverge in a manner that appears to be proportional to the bulk connectivity length. This suggests that a percolation transition in the bulk also drives a similar divergence observed in surfactant templated polyacrylamide gels at high surfactant concentrations.
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We show that smoothing of multiaffine surfaces that are generated by simulating a crosslinked polymer gel by a frustrated, triangular network of springs of random equilibrium lengths [G.M. Buend{i}a, S.J. Mitchell, P.A. Rikvold, Phys. Rev. E 66 (2002) 046119] changes the scaling behavior of the surfaces such that they become self-affine. The self-affine behavior is consistent with recent atomic force microscopy (AFM) studies of the surface structure of crosslinked polymer gels into which voids are introduced through templating by surfactant micelles [M. Chakrapani, S.J. Mitchell, D.H. Van Winkle, P.A. Rikvold, J. Colloid Interface Sci., in press]. The smoothing process mimics the effect of the AFM tip that tends to flatten the soft gel surfaces. Both the experimental and the simulated surfaces have a non-trivial scaling behavior on small length scales, with a crossover to scale-independent behavior on large scales.
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The discrete element method constitutes a general class of modeling techniques to simulate the microscopic behavior (i.e. at the particle scale) of granular/soil materials. We present a contact dynamics method, accounting for the cohesive nature of fine powders and soils. A modification of the model adjusted to capture the essential physical processes underlying the dynamics of generation and collapse of loose systems is able to simulate quicksand behavior of a collapsing soil material, in particular of a specific type, which we call living quicksand. We investigate the penetration behavior of an object for varying density of the material. We also investigate the dynamics of the penetration process, by measuring the relation between the driving force and the resulting velocity of the intruder, leading to a power law behavior with exponent 1/2, i.e. a quadratic velocity dependence of the drag force on the intruder.
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