Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userGlassy Dynamics of Simulated Polymer Melts: Coherent Scattering and Van Hove Functions Part II: Dynamics in the alpha-Relaxation Regime
161
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
Whereas the first part of this paper dealt with the relaxation in the beta-regime, this part investigates the final (alpha) relaxation of a simulated polymer melt consisting of short non-entangled chains above the critical temperature Tc of mode-coupling theory (MCT). We monitor the intermediate incoherent as well as the coherent chain and coherent melt scattering functions over a wide range of wave numbers q. Upon approaching Tc the coherent alpha-relaxation time of the melt increases strongly close to the maximum of the static structure factor of the melt. At q corresponding to the radius of gyration of the chain the melt relaxation time exhibits another maximum. The temperature dependence of the relaxation times is well described by a power-law with a q-dependent exponent in an intermediate temperature range. The time-temperature superposition principle of MCT is clearly bourne out in the whole range of wave numbers. An analysis of the alpha-decay using Kohlrausch-Williams-Watts (KWW) functions reveals that the collective melt KWW-stretching exponent and KWW-relaxation times are modulated with the structure factor. Furthermore, both incoherent and coherent KWW-times approach the large-q prediction of MCT at q comparable to the maximum of the structure factor. At small q a power law with exponent -3 is found for the coherent chain KWW-times similar to that of recent experiments.
rate research
Read More
We report results of molecular-dynamics simulations of a model polymer melt consisting of short non-entangled chains in the supercooled state above the critical temperature of mode-coupling theory (MCT). To analyse the dynamics of the system we computed the incoherent, collective chain and melt intermediate scattering functions as well as the Van Hove correlation functions. We find good evidence for the space-time factorization theorem of MCT. From the critical amplitudes we could derive typical length scales of the beta-dyamics. In an extensive quantitative analysis the leading order description of MCT was found to be accurate in the central beta-regime. Higher order corrections extend the validity of the MCT approximation to a greater time window. Indications of polymer specific effects on the length scale of the chains radius of gyration are visible in the beta-coefficients.
Significant progress was made in recent years in the understanding of the proton spin kinetics in polymer melts. Generally, the proton spin kinetics is determined by intramolecular and intermolecular magnetic dipole-dipole contributions of proton spins. During many decades it was postulated that the main contribution is a result of intramolecular magnetic dipole-dipole interactions of protons belonging to the same polymer segment. It appears that this postulate is far from reality. The relative weights of intra- and intermolecular contributions are time dependent and sensitive to details of polymer chain dynamics. It is shown that for isotropic models of polymer dynamics the influence of the intermolecular magnetic dipole-dipole interactions increases faster with increasing evolution time (i.e. decreasing frequency) than the corresponding influence of the intramolecular counterpart. On the other hand, an inverted situation is predicted by the tube-reptation model: here the influence of the intramolecular magnetic dipole-dipole interactions increases faster with time than the contribution from intermolecular interactions. The intermolecular contribution in the proton relaxation of polymer melts can experimentally be isolated using the isotope dilution technique and this opens a new perspective for experimental investigations of polymer dynamics by proton NMR.
We present an extensive set of simulation results for the stress relaxation in equilibrium and step-strained bead-spring polymer melts. The data allow us to explore the chain dynamics and the shear relaxation modulus, $G(t)$, into the plateau regime for chains with $Z=40$ entanglements and into the terminal relaxation regime for $Z=10$. Using the known (Rouse) mobility of unentangled chains and the melt entanglement length determined via the primitive path analysis of the microscopic topological state of our systems, we have performed parameter -free tests of several different tube models. We find excellent agreement for the Likhtman-McLeish theory using the double reptation approximation for constraint release, if we remove the contribution of high-frequency modes to contour length fluctuations of the primitive chain.
We generalize the force-level, microscopic, Nonlinear Langevin Equation (NLE) theory and its elastically collective generalization (ECNLE theory) of activated dynamics in bulk spherical particle liquids to address the influence of random particle pinning on structural relaxation. The simplest neutral confinement model is analyzed for hard spheres where there is no change of the equilibrium pair structure upon particle pinning. As the pinned fraction grows, cage scale dynamical constraints are intensified in a manner that increases with density. This results in the mobile particles becoming more transiently localized, with increases of the jump distance, cage scale barrier and NLE theory mean hopping time; subtle changes of the dynamic shear modulus are predicted. The results are contrasted with recent simulations. Similarities in relaxation behavior are identified in the dynamic precursor regime, including a roughly exponential, or weakly supra-exponential, growth of the alpha time with pinning fraction and a reduction of dynamic fragility. However, the increase of the alpha time with pinning predicted by the local NLE theory is too small, and severely so at very high volume fractions. The strong deviations are argued to be due to the longer range collective elasticity aspect of the problem which is expected to be modified by random pinning in a complex manner. A qualitative physical scenario is offered for how the three distinct aspects that quantify the elastic barrier may change with pinning. ECNLE theory calculations of the alpha time are then presented based on the simplest effective-medium-like treatment for how random pinning modifies the elastic barrier. The results appear to be consistent with most, but not all, trends seen in recent simulations. Key open problems are discussed with regards to both theory and simulation.
We have performed a thorough examination of the reorientational relaxation dynamics and the ionic charge transport of three typical deep eutectic solvents, ethaline, glyceline and reline by broadband dielectric spectroscopy. Our experiments cover a broad temperature range from the low-viscosity liquid down to the deeply supercooled state, allowing to investigate the significant influence of glassy freezing on the ionic charge transport in these systems. In addition, we provide evidence for a close coupling of the ionic conductivity in these materials to reorientational dipolar motions which should be considered when searching for deep eutectic solvents optimized for electrochemical applications.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
