We are engaged in an investigation of the relationship between the properties of BCG candidates and X-ray characteristics of their host clusters for a flux-limited sample of ~250 ACO clusters from the ROSAT all-sky survey. We aim to search for the convergence scale of bulk streaming flows within the ~300 Mpc defined by this sample. X-ray selection provides significant advantages over previous optically selected samples. No R-band magnitude-structure correlation is present in this sample. Furthermore, no correlation between R-band magnitude of the BCG candidate and X-ray luminosity of the host cluster is evident. The resultant scatter of 0.34 mag. is larger than in (corrected) optically selected samples. Hence, attempts to recover Local Group peculiar velocity vectors with respect to inertial frames defined by such samples via standard candle methods may have limited sensitivity.