The APM multicolor survey for bright z > 4 objects, covering 2500 deg^2 of sky to m(R)~19, resulted in the discovery of thirty-one quasars with z > 4. High signal-to-noise optical spectrophotometry at 5A resolution has been obtained for the twenty-eight quasars easily accessible from the northern hemisphere. These spectra have been surveyed to create new samples of high redshift Lyman-limit systems, damped Lyman-alpha absorbers, and metal absorption systems (e.g. CIV and MgII). In this paper we present the spectra, together with line lists of the detected absorption systems. The QSOs display a wide variety of emission and absorption line characteristics, with 5 exhibiting broad absorption lines and one with extremely strong emission lines (BR2248-1242). Eleven candidate damped Ly-alpha absorption systems have been identified covering the redshift range 2.8<z<4.4 (8 with z>3.5). An analysis of the measured redshifts of the high ionization emission lines with the low ionization lines shows them to be blueshifted by 430+/-60 km/s. In a previous paper (Storrie-Lombardi et. al. 1994) we discussed the redshift evolution of the Lyman limit systems catalogued here. In subsequent papers we will discuss the properties of the Ly-alpha forest absorbers and the redshift and column density evolution of the damped Ly-alpha absorbers.
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