We present the first high spatial resolution X-ray study of the massive star forming region NGC 6357, obtained in a 38 ks Chandra/ACIS observation. Inside the brightest constituent of this large HII region complex is the massive open cluster Pismis 24. It contains two of the brightest and bluest stars known, yet remains poorly studied; only a handful of optically bright stellar members have been identified. We investigate the cluster extent and Initial Mass Function and detect ~800 X-ray sources with a limiting sensitivity of 10^{30} ergs s^{-1}; this provides the first reliable probe of the rich intermediate-mass and low-mass population of this massive cluster, increasing the number of known members from optical study by a factor of ~50. The high luminosity end (log L_h[2-8 keV]ge 30.3 ergs s^{-1}) of the observed X-ray luminosity function in NGC 6357 is clearly consistent with a power law relation as seen in the Orion Nebula Cluster and Cepheus B, yielding the first estimate of NGC 6357s total cluster population, a few times the known Orion population. We investigate the structure of the cluster, finding small-scale substructures superposed on a spherical cluster with 6 pc extent, and discuss its relationship to the nebular morphology. The long-standing Lx - 10^{-7}L_{bol} correlation for O stars is confirmed. Twenty-four candidate O stars and one possible new obscured massive YSO or Wolf-Rayet star are presented. Many cluster members are estimated to be intermediate-mass stars from available infrared photometry (assuming an age of 1 Myr), but only a few exhibit K-band excess. We report the first detection of X-ray emission from an Evaporating Gaseous Globule at the tip of a molecular pillar; this source is likely a B0-B2 protostar.
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