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On the Disalignment of Interstellar Grains

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 Publication date 2006
  fields Physics
and research's language is English




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Several mechanisms have been proposed to explain the alignment of grains with the interstellar magnetic field, including paramagnetic dissipation, radiative torques, and supersonic gas-grain streaming. These must compete with disaligning processes, including randomly directed torques arising from collisions with gas atoms. I describe a novel disalignment mechanism for grains that have a time-varying electric dipole moment and that drift across the magnetic field. Depending on the drift speed, this mechanism may yield a much shorter disalignment timescale than that associated with random gas atom impacts. For suprathermally rotating grains, the new disaligning process may be more potent for carbonaceous dust than for silicate dust. This could result in efficient alignment for silicate grains but poor alignment for carbonaceous grains.

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The degree to which interstellar grains align with respect to the interstellar magnetic field depends on disaligning as well as aligning mechanisms. For decades, it was assumed that disalignment was due primarily to the random angular impulses a grain receives when colliding with gas-phase atoms. Recently, a new disalignment mechanism has been considered, which may be very potent for a grain that has a time-varying electric dipole moment and drifts across the magnetic field. We provide quantitative estimates of the disalignment times for silicate grains with size > approximately 0.1 micron. These appear to be shorter than the time-scale for alignment by radiative torques, unless the grains contain superparamagnetic inclusions.
Our understanding of the nature of interstellar grains has evolved considerably over the past half century with the present author and Fred Hoyle being intimately involved at several key stages of progress. The currently fashionable graphite-silicate-organic grain model has all its essential aspects unequivocally traceable to original peer-reviewed publications by the author and/or Fred Hoyle. The prevailing reluctance to accept these clear-cut priorities may be linked to our further work that argued for interstellar grains and organics to have a biological provenance - a position perceived as heretical. The biological model, however, continues to provide a powerful unifying hypothesis for a vast amount of otherwise disconnected and disparate astronomical data.
Interstellar dust grain alignment causes polarization from UV to mm wavelengths, allowing the study of the geometry and strength of the magnetic field. Over last couple of decades observations and theory have led to the establishment of the Radiative Alignment Torque (RAT) mechanism as leading candidate to explain the effect. With a quantitatively well constrained theory, polarization can be used not only to study the interstellar magnetic field, but also the dust and other environmental parameters. Photo-dissociation Regions (PDRs), with their intense, anisotropic radiation fields, consequent rapid $rm H_{2}$ formation, and high spatial density-contrast provide a rich environment for such studies. Here we discuss an expanded optical, NIR, and mm-wave study of the IC,63 nebula, showing strong $rm H_{2}$ formation-enhanced alignment and the first direct empirical evidence for disalignment due to gas-grain collisions using high-resolution $rm HCO^{+}$(J=1-0) observations. We find that relative amount of polarization is marginally anti-correlated with column density of $rm HCO^{+}$. However, separating the lines of sight of optical polarimetry into those behind, or in front of, a dense clump as seen from $gamma$ Cas, the distribution separates into two well defined sets, with data corresponding to enquote{shaded} gas having a shallower slope. This is expected if the decrease in polarization is caused by collisions since collisional disalignment rate is proportional to R$_Cpropto nsqrt{T}$. Ratios of the best-fit slopes for the enquote{illuminated} and enquote{shaded} samples of lines of sight agrees, within the uncertainties, with the square-root of the two-temperature H$_2$ excitation in the nebula seen by Thi et al. (2009).
In interstellar dust grains, internal processes dissipate rotational kinetic energy. The dissipation is accompanied by thermal fluctuations, which transfer energy from the vibrational modes to rotation. Together, these processes are known as internal relaxation. For the past several years, internal relaxation has been thought to give rise to thermal flipping, with profound consequences for grain alignment theory. I show that thermal flipping is not possible in the limit that the inertia tensor does not vary with time.
Molecules with an amide functional group resemble peptide bonds, the molecular bridges that connect amino acids, and may thus be relevant in processes that lead to the formation of life. In this study, the solid state formation of some of the smallest amides is investigated in the laboratory. To this end, CH$_{4}$:HNCO ice mixtures at 20 K are irradiated with far-UV photons, where the radiation is used as a tool to produce the radicals required for the formation of the amides. Products are identified and investigated with infrared spectroscopy and temperature programmed desorption mass spectrometry. The laboratory data show that NH$_{2}$CHO, CH$_{3}$NCO, NH$_{2}$C(O)NH$_{2}$, CH$_{3}$C(O)NH$_{2}$ and CH$_{3}$NH$_{2}$ can simultaneously be formed. The NH$_{2}$CO radical is found to be key in the formation of larger amides. In parallel, ALMA observations towards the low-mass protostar IRAS 16293-2422B are analysed in search of CH$_{3}$NHCHO (N-methylformamide) and CH$_{3}$C(O)NH$_{2}$ (acetamide). CH$_{3}$C(O)NH$_{2}$ is tentatively detected towards IRAS 16293-2422B at an abundance comparable with those found towards high-mass sources. The combined laboratory and observational data indicates that NH$_{2}$CHO and CH$_{3}$C(O)NH$_{2}$ are chemically linked and form in the ice mantles of interstellar dust grains. A solid-state reaction network for the formation of these amides is proposed.
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