Identifying the processes that determine the initial mass function of stars (IMF) is a fundamental problem in star formation theory. One of the major uncertainties is the exact chemical state of the star forming gas and its influence on the dynamical evolution. Most simulations of star forming clusters use an isothermal equation of state (EOS). However, theoretical predictions and observations suggest that the effective polytropic exponent gamma in the EOS varies with density. We address these issues and study the effect of a piecewise polytropic EOS on the formation of stellar clusters in turbulent, self-gravitating molecular clouds using three-dimensional, smoothed particle hydrodynamics simulations. To approximate the results of published predictions of the thermal behavior of collapsing clouds, we increase the polytropic exponent gamma from 0.7 to 1.1 at some chosen density n_c, which we vary. The change of thermodynamic state at n_c selects a characteristic mass scale for fragmentation M_ch, which we relate to the peak of the observed IMF. Our investigation generally supports the idea that the distribution of stellar masses depends mainly on the thermodynamic state of the star-forming gas. The thermodynamic state of interstellar gas is a result of the balance between heating and cooling processes, which in turn are determined by fundamental atomic and molecular physics and by chemical abundances. Given the abundances, the derivation of a characteristic stellar mass can thus be based on universal quantities and constants.
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