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Register a new userDeuterium chemistry in the primordial gas
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We review and update some aspects of deuterium chemistry in the post-recombination Universe with particular emphasis on the formation and destruction of HD. We examine in detail the available theoretical and experimental data for the leading reactions of deuterium chemistry and we highlight the areas where improvements in the determination of rate coefficients are necessary to reduce the remaining uncertainties. We discuss the cooling properties of HD and the modifications to the standard cooling function introduced by the presence of the cosmological radiation field. Finally, we consider the effects of deuterium chemistry on the dynamical collapse of primordial clouds in a simple ``top-hat scenario, and we speculate on the minimum mass a cloud must have in order to be able to cool in a Hubble time.
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High levels of deuterium fractionation in gas-phase molecules are usually associated with cold regions, such as prestellar cores. Significant fractionation ratios are also observed in hot environments such as hot cores or hot corinos, where they are believed to be produced by the evaporation of the icy mantles surrounding dust grains, and thus are remnants of a previous cold (either gas-phase or grain surface) chemistry. The recent detection of DCN towards the Orion Bar, in a clump at a characteristic temperature of 70K, has shown that high deuterium fractionation can also be detected in PDRs. The Orion Bar clumps thus appear as a good environment for the observational study of deuterium fractionation in luke-warm gas, allowing to validate chemistry models in a different temperature range, where dominating fractionation processes are predicted to be different than in cold gas (< 20K). We aimed at studying observationally in detail the chemistry at work in the Orion Bar PDR, to understand if DCN is produced by ice mantle evaporation, or is the result of warm gas-phase chemistry, involving the CH2D+ precursor ion (which survives higher temperatures than the usual H2D+ precursor). Using the APEX and the IRAM 30m telescopes, we targetted selected deuterated species towards two clumps in the Orion Bar. We confirmed the detection of DCN and detected two new deuterated molecules (DCO+ and HDCO) towards one clump in the Orion Bar PDR. Significant deuterium fractionations are found for HCN and H2CO, but a low fractionation in HCO+. We also give upper limits for other molecules relevant for the deuterium chemistry. (...) We show evidence that warm deuterium chemistry driven by CH2D+ is at work in the clumps.
Deuterium abundances measured recently from QSO absorption-line systems lie in the range from 3 10^{-5} to 3 10^{-4}, which shed some questions on standard big bang theory. We show that this discordance may simply be an artifact caused by inadequate analysis ignoring spatial correlations in the velocity field in turbulent media. The generalized procedure (accounting for such correlations) is suggested to reconcile the D/H measurements. An example is presented based on two high-resolution observations of Q1009+2956 (low D/H) [1,2] and Q1718+4807 (high D/H) [8,9]. We show that both observations are compatible with D/H = 4.1 - 4.6 10^{-5}, and thus support SBBN. The estimated mean value <D/H> = 4.4 10^{-5} corresponds to the baryon-to-photon ratio during SBBN eta = 4.4 10^{-10} which yields the present-day baryon density Omega_b h^2 = 0.015.
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Sergei A. Levshakov (National Astronomical Observatory
, Japan andn Ioffe Institute
, St. Petersburg
1997
The current status of extragalactic deuterium abundance is discussed using two examples of `low and `high D/H measurements. We show that the discordance of these two types of D abundances may be a consequence of the spatial correlations in the stochastic velocity field. Within the framework of the generalized procedure (accounting for such effects) one finds good agreement between different observations and the theoretical predictions for standard big bang nucleosynthesis (SBBN). In particular, we show that the deuterium absorption seen at z = 2.504 toward Q1009+2956 and the H+D Ly-alpha profile observed at z = 0.701 toward Q1718+4807 are compatible with D/H $sim 4.1 - 4.6times10^{-5}$. This result supports SBBN and, thus, no inhomogeneity is needed. The problem of precise D/H measurements is discussed.
We report the discovery of deuterium absorption in the very metal-poor ([Fe/H] = -2.88) damped Lyman-alpha system at z_abs = 3.06726 toward the QSO SDSS J1358+6522. On the basis of 13 resolved D I absorption lines and the damping wings of the H I Lyman alpha transition, we have obtained a new, precise measure of the primordial abundance of deuterium. Furthermore, to bolster the present statistics of precision D/H measures, we have reanalyzed all of the known deuterium absorption-line systems that satisfy a set of strict criteria. We have adopted a blind analysis strategy (to remove human bias), and developed a software package that is specifically designed for precision D/H abundance measurements. For this reanalyzed sample of systems, we obtain a weighted mean of (D/H)_p = (2.53 +/- 0.04) x 10^-5, corresponding to a Universal baryon density100 Omega_b h^2 = 2.202 +/- 0.046 for the standard model of Big Bang Nucleosynthesis. By combining our measure of (D/H)_p with observations of the cosmic microwave background, we derive the effective number of light fermion species, N_eff = 3.28 +/- 0.28. We therefore rule out the existence of an additional (sterile) neutrino (i.e. N_eff = 4.046) at 99.3 percent confidence (2.7 sigma), provided that N_eff and the baryon-to-photon ratio (eta_10) did not change between BBN and recombination. We also place a strong bound on the neutrino degeneracy parameter, xi_D = +0.05 +/- 0.13 based only on the CMB+(D/H)_p observations. Combining xi_D with the current best literature measure of Y_p, we find |xi| <= +0.062. In future, improved measurements of several key reaction rates, in particular d(p,gamma)3He, and further measures of (D/H)_p with a precision comparable to those considered here, should allow even more stringent limits to be placed on new physics beyond the standard model.
We report a reanalysis of a near-pristine absorption system, located at a redshift z_abs=2.52564 toward the quasar Q1243+307, based on the combination of archival and new data obtained with the HIRES echelle spectrograph on the Keck telescope. This absorption system, which has an oxygen abundance [O/H]=-2.769+/-0.028 (~1/600 of the Solar abundance), is among the lowest metallicity systems currently known where a precise measurement of the deuterium abundance is afforded. Our detailed analysis of this system concludes, on the basis of eight D I absorption lines, that the deuterium abundance of this gas cloud is log_10(D/H) = -4.622+/-0.015, which is in very good agreement with the results previously reported by Kirkman et al. (2003), but with an improvement on the precision of this single measurement by a factor of ~3.5. Combining this new estimate with our previous sample of six high precision and homogeneously analyzed D/H measurements, we deduce that the primordial deuterium abundance is log_10(D/H)_P = -4.5974+/-0.0052 or, expressed as a linear quantity, (D/H)_P = (2.527+/-0.030)x10^-5; this value corresponds to a one percent determination of the primordial deuterium abundance. Combining our result with a BBN calculation that uses the latest nuclear physics input, we find that the baryon density derived from BBN agrees to within 2 sigma of the latest results from the Planck CMB data.
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