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Register a new userDetection of C$_{3}$ in Diffuse Interstellar Clouds
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J.P. Maier
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The smallest polyatomic carbon chain, C$_{3}$, has been identified in interstellar clouds (A$_{v}sim$1 mag) towards $zeta$ Ophiuchi, 20 Aquilae, and $zeta$ Persei by detection of the origin band in its $A^{1}Pi_{u}-X^{1}Sigma^{+}_{g}$ electronic transition, near 4052AA. Individual rotational lines were resolved up to $J$=30 enabling the rotational level column densities and temperature distributions to be determined. The inferred limits for the total column densities ($sim$1 to 2$times10^{12}$ cm$^{-2}$) offer a strong incentive to laboratory and astrophysical searches for the longer carbon chains. Concurrent searches for C$_2^{+}$, C$_2^{-}$ and C$_3^{-}$ were negative but provide sensitive estimates for their maximum column densities.
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We investigate the diffuse interstellar band (DIB) spectrum in the interstellar medium of M31. The DEIMOS spectrograph of the W. M. Keck observatory was used to make optical spectroscopic observations of two supergiant stars, MAG 63885 and MAG 70817, in the vicinity of the OB78 association in M31 where the metallicity is approximately equal to solar. The 5780, 5797, 6203, 6283 and 6613 DIBs are detected in both sightlines at velocities matching the M31 interstellar Na I absorption. The spectra are classified and interstellar reddenings are derived for both stars. Diffuse interstellar band (DIB) equivalent widths and radial velocities are presented. The spectrum of DIBs observed in M31 towards MAG 63885 is found to be similar to that observed in the Milky Way. Towards MAG 70817 the DIB equivalent widths per unit reddening are about three times the Galactic average. Compared to observations elsewhere in the Universe, relative to reddening the M31 ISM in the vicinity of OB78 is apparently a highly favourable environment for the formation of DIB carriers.
Context. Insight into the conditions that drive the physics and chemistry in interstellar clouds is gained from determining the abundance and charge state of their components. Aims. We propose an evaluation of the C60:C60+ ratio in diffuse and translucent interstellar clouds that exploits electronic absorption bands so as not to rely on ambiguous IR emission measurements. Methods. The ratio is determined by analyzing archival spectra and literature data. Information on the cation population is obtained from published characteristics of the main diffuse interstellar bands attributed to C60+ and absorption cross sections already reported for the vibronic bands of the cation. The population of neutral molecules is described in terms of upper limit because the relevant vibronic bands of C60 are not brought out by observations. We revise the oscillator strengths reported for C60 and measure the spectrum of the molecule isolated in Ne ice to complete them. Results. We scale down the oscillator strengths for absorption bands of C60 and find an upper limit of approximately 1.3 for the C60:C60+ ratio. Conclusions. We conclude that the fraction of neutral molecules in the buckminsterfullerene population of diffuse and translucent interstellar clouds may be notable despite the non-detection of the expected vibronic bands. More certainty will require improved laboratory data and observations.
We confirm and discuss recently discovered cold HI clouds with column densities among the lowest ever detected. The column densities of Cold Neutral Medium (CNM) towards 3C286 and 3C287 are ~10^18 cm^-2, below an observational lower limit, and also below tiny-scale-atomic clouds detected by VLBI and time-variable profiles against pulsars. These column densities are close to the minimum imposed by thermal evaporation. The fractions of the CNM to total HI towards 3C286 and 3C287 are ~4% and <2%, respectively. We discuss the CNM fraction and the CNM clouds in relation to several theoretical models.
Emission of fullerenes in their infrared vibrational bands has been detected in space near hot stars. The proposed attribution of the diffuse interstellar bands at 9577 and 9632 AA to electronic transitions of the buckminsterfullerene cation (i.e. C$_{60}^+$ ) was recently supported by new laboratory data, confirming the presence of this species in the diffuse interstellar medium (ISM). In this letter, we present the detection, also in the diffuse ISM, of the 17.4 and 18.9 $mu$m emission bands commonly attributed to vibrational bands of neutral C$_{60}$. According to classical models that compute the charge state of large molecules in space, C$_{60}$ is expected to be mostly neutral in the diffuse ISM. This is in agreement with the abundances of diffuse C$_{60}$ we derive here from observations.
We report the first detection of C$^{15}$N in diffuse molecular gas from a detailed examination of CN absorption lines in archival VLT/UVES spectra of stars probing local diffuse clouds. Absorption from the C$^{15}$N isotopologue is confidently detected (at $gtrsim4sigma$) in three out of the four directions studied and appears as a very weak feature between the main $^{12}$CN and $^{13}$CN absorption components. Column densities for each CN isotopologue are determined through profile fitting, after accounting for weak additional line-of-sight components of $^{12}$CN, which are seen in the absorption profiles of CH and CH$^+$ as well. The weighted mean value of C$^{14}$N/C$^{15}$N for the three sight lines with detections of C$^{15}$N is $274pm18$. Since the diffuse molecular clouds toward our target stars have relatively high gas kinetic temperatures and relatively low visual extinctions, their C$^{14}$N/C$^{15}$N ratios should not be affected by chemical fractionation. The mean C$^{14}$N/C$^{15}$N ratio that we obtain should therefore be representative of the ambient $^{14}$N/$^{15}$N ratio in the local interstellar medium. Indeed, our mean value agrees well with that derived from millimeter-wave observations of CN, HCN, and HNC in local molecular clouds.
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