We find resolved interstellar O K, Ne K, and Fe L absorption spectra in the Chandra Low Energy Transmission Grating Spectrometer spectrum of the low mass X-ray binary X0614+091. We measure the column densities in O and Ne, and find direct spectroscopic constraints on the chemical state of the interstellar O. These measurements probably probe a low-density line of sight through the Galaxy and we discuss the results in the context of our knowledge of the properties of interstellar matter in regions between the spiral arms.