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Register a new userMolecules with ALMA at Planet-forming Scales (MAPS) XI: CN and HCN as Tracers of Photochemistry in Disks
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UV photochemistry in the surface layers of protoplanetary disks dramatically alters their composition relative to previous stages of star formation. The abundance ratio CN/HCN has long been proposed to trace the UV field in various astrophysical objects, however to date the relationship between CN, HCN, and the UV field in disks remains ambiguous. As part of the ALMA Large Program MAPS (Molecules with ALMA at Planet-forming Scales), we present observations of CN N=1-0 transitions at 0.3 resolution towards five disk systems. All disks show bright CN emission within $sim$50-150 au, along with a diffuse emission shelf extending up to 600 au. In all sources we find that the CN/HCN column density ratio increases with disk radius from about unity to 100, likely tracing increased UV penetration that enhances selective HCN photodissociation in the outer disk. Additionally, multiple millimeter dust gaps and rings coincide with peaks and troughs, respectively, in the CN/HCN ratio, implying that some millimeter substructures are accompanied by changes to the UV penetration in more elevated disk layers. That the CN/HCN ratio is generally high (>1) points to a robust photochemistry shaping disk chemical compositions, and also means that CN is the dominant carrier of the prebiotically interesting nitrile group at most disk radii. We also find that the local column densities of CN and HCN are positively correlated despite emitting from vertically stratified disk regions, indicating that different disk layers are chemically linked. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.
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Deuterium fractionation is dependent on various physical and chemical parameters. Thus, the formation location and thermal history of material in the solar system is often studied by measuring its D/H ratio. This requires knowledge about the deuteration processes operating during the planet formation era. We aim to study these processes by radially resolving the DCN/HCN (at 0.3 resolution) and N$_2$D$^+$/N$_2$H$^+$ (0.3 to 0.9) column density ratios toward the five protoplanetary disks observed by the Molecules with ALMA at Planet-forming scales (MAPS) Large Program. DCN is detected in all five sources, with one newly reported detection. N$_2$D$^+$ is detected in four sources, two of which are newly reported detections. We derive column density profiles that allow us to study the spatial variation of the DCN/HCN and N$_2$D$^+$/N$_2$H$^+$ ratios at high resolution. DCN/HCN varies considerably for different parts of the disks, ranging from $10^{-3}$ to $10^{-1}$. In particular, the inner disk regions generally show significantly lower HCN deuteration compared with the outer disk. In addition, our analysis confirms that two deuterium fractionation channels are active, which can alter the D/H ratio within the pool of organic molecules. N$_2$D$^+$ is found in the cold outer regions beyond $sim$50 au, with N$_2$D$^+$/N$_2$H$^+$ ranging between $10^{-2}$ and 1 across the disk sample. This is consistent with the theoretical expectation that N$_2$H$^+$ deuteration proceeds via the low-temperature channel only. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.
We observed HCO$^+$ $J=1-0$ and H$^{13}$CO$^+$ $J=1-0$ emission towards the five protoplanetary disks around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480 as part of the MAPS project. HCO$^+$ is detected and mapped at 0.3arcsec,resolution in all five disks, while H$^{13}$CO$^+$ is detected (SNR$>6 sigma$) towards GM Aur and HD 163296 and tentatively detected (SNR$>3 sigma$) towards the other disks by a matched filter analysis. Inside a radius of $Rsim 100$ au, the HCO$^+$ column density is flat or shows a central dip. At outer radii ($gtrsim 100$ au), the HCO$^+$ column density decreases outwards, while the column density ratio of HCO$^+$/CO is mostly in the range of $sim 10^{-5}-10^{-4}$. We derived the HCO$^+$ abundance in the warm CO-rich layer, where HCO$^+$ is expected to be the dominant molecular ion. At $Rgtrsim 100$ au, the HCO$^+$ abundance is $sim 3 times 10^{-11} - 3times 10^{-10}$, which is consistent with a template disk model with X-ray ionization. At the smaller radii, the abundance decreases inwards, which indicates that the ionization degree is lower in denser gas, especially inside the CO snow line, where the CO-rich layer is in the midplane. Comparison of template disk models with the column densities of HCO$^+$, N$_2$H$^+$, and N$_2$D$^+$ indicates that the midplane ionization rate is $gtrsim 10^{-18}$ s$^{-1}$ for the disks around IM Lup, AS 209, and HD 163296. We also find hints of an increased HCO$^+$ abundance around the location of dust continuum gaps in AS 209, HD 163296, and MWC 480. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.
The Molecules with ALMA at Planet-forming Scales (MAPS) Large Program provides a unique opportunity to study the vertical distribution of gas, chemistry, and temperature in the protoplanetary disks around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. By using the asymmetry of molecular line emission relative to the disk major axis, we infer the emission height ($z$) above the midplane as a function of radius ($r$). Using this method, we measure emitting surfaces for a suite of CO isotopologues, HCN, and C$_2$H. We find that $^{12}$CO emission traces the most elevated regions with $z/r > 0.3$, while emission from the less abundant $^{13}$CO and C$^{18}$O probes deeper into the disk at altitudes of $z/r lesssim 0.2$. C$_2$H and HCN have lower opacities and SNRs, making surface fitting more difficult, and could only be reliably constrained in AS 209, HD 163296, and MWC 480, with $z/r lesssim 0.1$, i.e., relatively close to the planet-forming midplanes. We determine peak brightness temperatures of the optically thick CO isotopologues and use these to trace 2D disk temperature structures. Several CO temperature profiles and emission surfaces show dips in temperature or vertical height, some of which are associated with gaps and rings in line and/or continuum emission. These substructures may be due to local changes in CO column density, gas surface density, or gas temperatures, and detailed thermo-chemical models are necessary to better constrain their origins and relate the chemical compositions of elevated disk layers with those of planet-forming material in disk midplanes. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.
Planets form and obtain their compositions in dust and gas-rich disks around young stars, and the outcome of this process is intimately linked to the disk chemical properties. The distributions of molecules across disks regulate the elemental compositions of planets, including C/N/O/S ratios and metallicity (O/H and C/H), as well as access to water and prebiotically relevant organics. Emission from molecules also encodes information on disk ionization levels, temperature structures, kinematics, and gas surface densities, which are all key ingredients of disk evolution and planet formation models. The Molecules with ALMA at Planet-forming Scales (MAPS) ALMA Large Program was designed to expand our understanding of the chemistry of planet formation by exploring disk chemical structures down to 10 au scales. The MAPS program focuses on five disks - around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480 - in which dust substructures are detected and planet formation appears to be ongoing. We observed these disks in 4 spectral setups, which together cover ~50 lines from over 20 different species. This paper introduces the ApJS MAPS Special Issue by presenting an overview of the program motivation, disk sample, observational details, and calibration strategy. We also highlight key results, including discoveries of links between dust, gas, and chemical sub-structures, large reservoirs of nitriles and other organics in the inner disk regions, and elevated C/O ratios across most disks. We discuss how this collection of results is reshaping our view of the chemistry of planet formation.
Sulfur-bearing molecules play an important role in prebiotic chemistry and planet habitability. They are also proposed probes of chemical ages, elemental C/O ratio, and grain chemistry processing. Commonly detected in diverse astrophysical objects, including the Solar System, their distribution and chemistry remain, however, largely unknown in planet-forming disks. We present CS ($2-1$) observations at $sim0.3$ resolution performed within the ALMA-MAPS Large Program toward the five disks around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. CS is detected in all five disks, displaying a variety of radial intensity profiles and spatial distributions across the sample, including intriguing apparent azimuthal asymmetries. Transitions of C$_2$S and SO were also serendipitously covered but only upper limits are found. For MWC 480, we present complementary ALMA observations at $sim0.5$, of CS, $^{13}$CS, C$^{34}$S, H$_2$CS, OCS, and SO$_2$. We find a column density ratio N(H$_{2}$CS)/N(CS)$sim2/3$, suggesting that a substantial part of the sulfur reservoir in disks is in organic form (i.e., C$_x$H$_y$S$_z$). Using astrochemical disk modeling tuned to MWC 480, we demonstrate that $N$(CS)/$N$(SO) is a promising probe for the elemental C/O ratio. The comparison with the observations provides a super-solar C/O. We also find a depleted gas-phase S/H ratio, suggesting either that part of the sulfur reservoir is locked in solid phase or that it remains in an unidentified gas-phase reservoir. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.
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