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Molecules with ALMA at Planet-forming Scales (MAPS). IX. Distribution and Properties of the Large Organic Molecules HC$_3$N, CH$_3$CN, and $c$-C$_3$H$_2$

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 Added by John Ilee
 Publication date 2021
  fields Physics
and research's language is English




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The precursors to larger, biologically-relevant molecules are detected throughout interstellar space, but determining the presence and properties of these molecules during planet formation requires observations of protoplanetary disks at high angular resolution and sensitivity. Here we present 0.3 observations of HC$_3$N, CH$_3$CN, and $c$-C$_3$H$_2$ in five protoplanetary disks observed as part of the Molecules with ALMA at Planet-forming Scales (MAPS) Large Program. We robustly detect all molecules in four of the disks (GM Aur, AS 209, HD 163296 and MWC 480) with tentative detections of $c$-C$_3$H$_2$ and CH$_3$CN in IM Lup. We observe a range of morphologies -- central peaks, single or double rings -- with no clear correlation in morphology between molecule nor disk. Emission is generally compact and on scales comparable with the millimetre dust continuum. We perform both disk-integrated and radially-resolved rotational diagram analysis to derive column densities and rotational temperatures. The latter reveals 5-10 times more column density in the inner 50-100 au of the disks when compared with the disk-integrated analysis. We demonstrate that CH$_3$CN originates from lower relative heights in the disks when compared with HC$_3$N, in some cases directly tracing the disk midplane. Finally, we find good agreement between the ratio of small to large nitriles in the outer disks and comets. Our results indicate that the protoplanetary disks studied here are host to significant reservoirs of large organic molecules, and that this planet- and comet-building material can be chemically similar to that in our own Solar System. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement Series.



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The Molecules with ALMA at Planet-forming Scales (MAPS) Large Program provides a detailed, high resolution (${sim}$10-20 au) view of molecular line emission in five protoplanetary disks at spatial scales relevant for planet formation. Here, we present a systematic analysis of chemical substructures in 18 molecular lines toward the MAPS sources: IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. We identify more than 200 chemical substructures, which are found at nearly all radii where line emission is detected. A wide diversity of radial morphologies - including rings, gaps, and plateaus - is observed both within each disk and across the MAPS sample. This diversity in line emission profiles is also present in the innermost 50 au. Overall, this suggests that planets form in varied chemical environments both across disks and at different radii within the same disk. Interior to 150 au, the majority of chemical substructures across the MAPS disks are spatially coincident with substructures in the millimeter continuum, indicative of physical and chemical links between the disk midplane and warm, elevated molecular emission layers. Some chemical substructures in the inner disk and most chemical substructures exterior to 150 au cannot be directly linked to dust substructure, however, which indicates that there are also other causes of chemical substructures, such as snowlines, gradients in UV photon fluxes, ionization, and radially-varying elemental ratios. This implies that chemical substructures could be developed into powerful probes of different disk characteristics, in addition to influencing the environments within which planets assemble. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.
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The elemental composition of the gas and dust in a protoplanetary disk influences the compositions of the planets that form in it. We use the Molecules with ALMA at Planet-forming Scales (MAPS) data to constrain the elemental composition of the gas at the locations of potentially forming planets. The elemental abundances are inferred by comparing source-specific gas-grain thermochemical models, with variable C/O ratios and small-grain abundances, from the DALI code with CO and C2H column densities derived from the high-resolution observations of the disks of AS 209, HD 163296, and MWC 480. Elevated C/O ratios (~2.0), even within the CO ice line, are necessary to match the inferred C2H column densities, over most of the pebble disk. Combined with constraints on the CO abundances in these systems, this implies that both the O/H and C/H ratios in the gas are substellar by a factor of 4-10, with the O/H depleted by a factor of 20-50, resulting in the high C/O ratios. This necessitates that even within the CO ice line, most of the volatile carbon and oxygen is still trapped on grains in the midplane. Planets accreting gas in the gaps of the AS 209, HD 163296, and MWC 480 disks will thus acquire very little carbon and oxygen after reaching the pebble isolation mass. In the absence of atmosphere-enriching events, these planets would thus have a strongly substellar O/H and C/H and superstellar C/O atmospheric composition.
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