The realization of spin-orbit coupling (SOC) in ultracold atoms has triggered an intensive exploring of topological superfluids in the degenerate Fermi gases based on mean-field theory, which has not yet been reported in experiments. Here, we demonstrate the topological phase transitions in the system via the numerically exact quantum Monte Carlo method. Without prior assumptions, our unbiased real-space calculation shows that spin-orbit coupling can stabilize an unconventional pairing in the weak SOC regime, in which the Fulde-Ferrell-Larkin-Ovchinnikov pairing coexists with the Bardeen-Cooper-Schrieffer pairing. Furthermore, we use the jumps in the spin polarization at the time-reversal invariant momenta to qualify the topological phase transition, where we find the critical exponent deviated from the mean-field theory. Our results pave the way for the searching of unconventional pairing and topological superfluids with degenerate Fermi gases.
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